Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester, (1R,2R,3S,4S)-

Base Information

Chemical Name:Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester, (1R,2R,3S,4S)-
CAS No.:878560-03-3
Molecular Formula:C34H43NO6
Molecular Weight:561.719
Hs Code.:

Bicyclo[2.2.1]heptane-2-carboxylic acid,
2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-,
(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester,
(1R,2R,3S,4S)-

Synonyms:

Suppliers and Price of Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester, (1R,2R,3S,4S)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester, (1R,2R,3S,4S)-

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Technology Process of Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester, (1R,2R,3S,4S)-

There total 5 articles about Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-(benzoylamino)-3-[(ethoxycarbonyl)oxy]-, (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl ester, (1R,2R,3S,4S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 878560-01-1
(-)-8-phenylmenthyl 2-(benzoylamino)-3-(ethoxycarbonyloxy)bicyclo[2.2.1]hept-5-ene-2-carboxylate

: 878560-03-3
(-)-8-phenylmenthyl (1R,2R,3S,4S)-2-(benzoylamino)-3-(ethoxycarbonyloxy)bicyclo[2.2.1]heptane-2-carboxylate

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; at 25 ℃; for 2h; under 760 Torr;
DOI:10.1016/j.tetasy.2005.11.011

Reference yield:

: 65253-04-5
(-)-8-phenylmenthol

: 878560-03-3
(-)-8-phenylmenthyl (1R,2R,3S,4S)-2-(benzoylamino)-3-(ethoxycarbonyloxy)bicyclo[2.2.1]heptane-2-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 70 percent / (Bu₂SnCl)2O / toluene / 24 h / Heating

2: 90 percent / triethylamine / CH₂Cl₂ / 3 h / -10 °C

3: 76 percent / Mg(ClO₄)2 / toluene / 36 h / sonication

4: 96 percent / H₂ / Pd/C / ethanol / 2 h / 25 °C / 760 Torr

With magnesium(II) perchlorate; hydrogen; 1,3-dichlorotetrabutyldistannoxane; triethylamine; palladium on activated charcoal; In ethanol; dichloromethane; toluene; 3: Diels-Alder reaction;
DOI:10.1016/j.tetasy.2005.11.011

Reference yield:

: 878559-99-0
(-)-8-phenylmenthyl (Z)-2-(benzoylamino)-3-hydroxyacrylate

: 878560-03-3
(-)-8-phenylmenthyl (1R,2R,3S,4S)-2-(benzoylamino)-3-(ethoxycarbonyloxy)bicyclo[2.2.1]heptane-2-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / triethylamine / CH₂Cl₂ / 3 h / -10 °C

2: 76 percent / Mg(ClO₄)2 / toluene / 36 h / sonication

3: 96 percent / H₂ / Pd/C / ethanol / 2 h / 25 °C / 760 Torr

With magnesium(II) perchlorate; hydrogen; triethylamine; palladium on activated charcoal; In ethanol; dichloromethane; toluene; 2: Diels-Alder reaction;
DOI:10.1016/j.tetasy.2005.11.011