N-(2-chloroprop-2-enyl)aniline

Base Information

• Chemical Name: N-(2-chloroprop-2-enyl)aniline
• CAS No.: 15332-67-9
• Molecular Formula: C9H10 Cl N
• Molecular Weight: 167.638
• Hs Code.: 2921420090
• Mol file: 15332-67-9.mol

Synonyms:Aniline,N-(2-chloroallyl)- (6CI,8CI); Benzenamine, N-(2-chloro-2-propenyl)- (9CI); NSC53440

Chemical Property of N-(2-chloroprop-2-enyl)aniline

Chemical Property:

• Vapor Pressure: 0.00719mmHg at 25°C
• Boiling Point: 269.6°C at 760 mmHg
• PKA: 1.40±0.50(Predicted)
• Flash Point: 116.8°C
• PSA: 12.03000
• Density: 1.131g/cm³
• LogP: 2.92400

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-(2-chloroprop-2-enyl)aniline

There total 7 articles about N-(2-chloroprop-2-enyl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

3-iodo-2-chloropropene (39557-31-8) + aniline (62-53-3) → N,N-bis(2-chloroallyl)aniline (13694-03-6) + N-(2-chloroprop-2-en-1-yl)-aniline (15332-67-9)

Guidance literature:

With potassium fluoride; In acetonitrile; for 6h; Heating;

DOI:10.1021/ol070890o

Reference yield: 84.0%

2,3-Dichloroprop-1-ene (78-88-6) + aniline (62-53-3) → N,N-bis(2-chloroallyl)aniline (13694-03-6) + N-(2-chloroprop-2-en-1-yl)-aniline (15332-67-9)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 85 - 95 ℃; for 5h; Yields of byproduct given;

Reference yield: 82.0%

2,3-Dichloroprop-1-ene (78-88-6) + aniline (62-53-3) → N-(2-chloroprop-2-en-1-yl)-aniline (15332-67-9)

Guidance literature:

In water; at 50 - 65 ℃; for 4.5h;

DOI:10.1039/P19890000553

upstream raw materials:

2,3-Dichloroprop-1-ene

aniline

1-(2-Chloro-allyloxy)-4-methoxy-benzene

1,2,3-trichloropropane

Downstream raw materials:

2-methyl-1H-indole

N-(2-chloro-allyl)-4-nitroso-aniline

chloro-acetic acid-[N-(2-chloro-allyl)-anilide]

N-(2-chloroallyl)-2,2,2-trifluoro-N-phenylacetamide