TRICYCLO[2.2.1.0(2,6)]HEPTANE

Base Information

• Chemical Name: TRICYCLO[2.2.1.0(2,6)]HEPTANE
• CAS No.: 279-19-6
• Molecular Formula: C7H10
• Molecular Weight: 94.1564
• Hs Code.: 2902199090
• Mol file: 279-19-6.mol

Synonyms:NSC 78724;Nortricyclen; Nortricyclene

Chemical Property of TRICYCLO[2.2.1.0(2,6)]HEPTANE

Chemical Property:

• Vapor Pressure: 30mmHg at 25°C
• Refractive Index: 1.5480 (estimate)
• Boiling Point: 108.7°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.091g/cm³
• LogP: 1.66230

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRICYCLO[2.2.1.0(2,6)]HEPTANE

There total 60 articles about TRICYCLO[2.2.1.0(2,6)]HEPTANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2-norbornyl tosylate (959-42-2) → nortricyclane (279-19-6) + exo-2-norbornanol (497-37-0)

Guidance literature:

With water; In 1,4-dioxane; Product distribution;

DOI:10.1002/hlca.19880710203

Reference yield: 93.0%

endo 2-norbornyl tosylate (840-90-4) → nortricyclane (279-19-6) + exo-2-norbornanol (497-37-0)

Guidance literature:

With water; In 1,4-dioxane; Product distribution;

DOI:10.1002/hlca.19880710203

Reference yield:

endo 2-norbornyl tosylate (840-90-4) → tricyclo<2.2.1.02,6>heptane (279-19-6) + exo-2-norbornanol (497-37-0)

Guidance literature:

With water; In ethanol; at 70 ℃; Thermodynamic data; Kinetics; other solvent, ΔH(excit.), ΔS(excit.), substituent effect;

DOI:10.1002/hlca.19810640735

upstream raw materials:

quinoline

exo-2-bromonorbornane

tetrahydrofuran

sodium phenoxide

Downstream raw materials:

3-Cyclohexyl-nortricyclen

4-ethynylcyclopentene

di(3-nortricyclanylidene)hydrazine

3-nortricyclanol