cyclohepta-1,3,5-triene - trihydroxy-lambda~3~-chlorane oxide (1:1)

Base Information

• Chemical Name: cyclohepta-1,3,5-triene - trihydroxy-lambda~3~-chlorane oxide (1:1)
• CAS No.: 25230-72-2
• Molecular Formula: C7H7ClO4
• Molecular Weight: 190.583
• Mol file: 25230-72-2.mol

Synonyms:Cycloheptatrienylium, perchlorate (8CI 9CI);Cycloheptatrienylium perchlorate;

Chemical Property of cyclohepta-1,3,5-triene - trihydroxy-lambda~3~-chlorane oxide (1:1)

Chemical Property:

• Vapor Pressure: 21.6mmHg at 25°C
• Boiling Point: 116.5°Cat760mmHg
• Flash Point: 26.7°C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cyclohepta-1,3,5-triene - trihydroxy-lambda~3~-chlorane oxide (1:1)

There total 5 articles about cyclohepta-1,3,5-triene - trihydroxy-lambda~3~-chlorane oxide (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.1%

7,9-diphenyl-8-(2,4,6-cycloheptatrienyl)-8H-cyclopentacenaphthylene (115205-68-0) → ditrityl peroxide (596-30-5) + 7,9-diphenylcyclopenta[a]acenaphthadiene (33836-47-4) + tropylium perchlorate (25230-72-2) + 7,9,7',9'-Tetraphenyl-8H,8'H-[8,8']bi[cyclopenta[a]acenaphthylenyl] (115205-69-1)

Guidance literature:

With triphenylmethyl perchlorate; In dichloromethane; acetonitrile; for 0.333333h;

DOI:10.1021/jo00251a036

Reference yield:

Cyclohepta-1,3,5-triene (544-25-2) → tropylium perchlorate (25230-72-2)

Guidance literature:

With triphenylmethyl perchlorate; acetonitrile; at 20 ℃;

DOI:10.1021/ja01573a084

Reference yield:

cyclohepta-2,4,6-triene-1-carbonitrile (13612-59-4) → tropylium perchlorate (25230-72-2)

Guidance literature:

With nitromethane; silver perchlorate; at 85 - 90 ℃;

DOI:10.1039/jr9590002438

upstream raw materials:

cyclohepta-2,4,6-triene-1-carbonitrile

cycloheptatriene-7-carbonyl chloride

Cyclohepta-1,3,5-triene

7,9-diphenyl-8-(2,4,6-cycloheptatrienyl)-8H-cyclopentacenaphthylene

Downstream raw materials:

phenol

Refernces

• 1、 Marichev, Konstantin A.,Korotkikh, Nikolai I.,Cowley, Alan H.,Saberov, Vagiz Sh,Glinyanaya, Nataliya V.,Rayenko, Gennady F.,Shvaika, Oles P.. "Highly efficient carbene and polycarbene catalysis of the transesterification reaction". supporting information. p. 365 - 376. Retrieved 2018/05/07.