596-30-5

Basic information

• Product Name: Peroxide,bis(triphenylmethyl) (9CI)
• Synonyms: Tritylperoxide (6CI,7CI,8CI); Bis(triphenylmethyl) peroxide; NSC 131577;Triphenylmethyl peroxide
• CAS NO: 596-30-5
• Molecular Formula: C38H30 O2
• Molecular Weight: 518.655
• Mol File: 596-30-5.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Peroxide,bis(triphenylmethyl) (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide,bis(triphenylmethyl) (9CI)(596-30-5)
• EPA Substance Registry System: Peroxide,bis(triphenylmethyl) (9CI)(596-30-5)

Safety Data

• Hazardous Substances Data: 596-30-5(Hazardous Substances Data)

Usage

General Description

Peroxide, bis(triphenylmethyl) (9CI) is a chemical compound with the formula (C19H15)2O2. It is a peroxide derivative that contains two triphenylmethyl groups, which are also referred to as trityl groups. Peroxide,bis(triphenylmethyl) (9CI) is a white, crystalline solid that is insoluble in water but soluble in organic solvents. Peroxide, bis(triphenylmethyl) is used as an oxidizing reagent in organic synthesis and can be employed in the preparation of various organic compounds. It is also used as a polymerization initiator and can participate in radical reactions. However, it should be handled with caution, as peroxides are generally unstable and can be hazardous if mishandled or mixed with incompatible substances.

Upstream product

• 56-23-5 tetrachloromethane 
• 54040-66-3 benzoyl-trityl-diazene 
• 60-29-7 diethyl ether 
• 6652-29-5 2-phenoxy-1,2-diphenylethanone 
• 4303-71-3 triphenylmethyl sodium 
• 595-91-5 triphenylacetic acid 
• 104933-75-7 triphenylmethylhydrazine 
• 76-83-5 trityl chloride 
• 34324-92-0 triphenylmethylmagnesium chloride 
• 768-66-1 2,2,6,6-tetramethyl-piperidine 
• 24165-03-5 tritylsulfenyl chloride 
• 519-73-3 triphenylmethane 
• 10409-54-8 2-bromo-2-methyl-1-phenyl-propan-1-one 
• 124-41-4 sodium methylate 

Downstream Products

• 42732-53-6 1,2-diphenoxy-1,1,2,2-tetraphenylethane 
• 519-73-3 triphenylmethane 
• 2051-90-3 Dichlorodiphenylmethane 
• 76-83-5 trityl chloride 
• 632-51-9 1,1,2,2-tetraphenylethylene 
• 789-24-2 9-Phenylfluorene 
• 596-43-0 bromo-triphenyl-methane 
• 831-18-5 ditropenyl 
• 115226-95-4 8-Cyclohepta-1,3,6-trienyl-7,9-diphenyl-8H-cyclopenta[a]acenaphthylene 
• 115205-69-1 7,9,7',9'-Tetraphenyl-8H,8'H-[8,8']bi[cyclopenta[a]acenaphthylenyl] 
• 119-61-9 benzophenone 
• 5447-80-3 trityl phenoxide 
• 59550-02-6 benzophenone diphenyl ketal 
• 108-95-2 phenol 

Relevant articles and documents

Reduction of Dioxygen by Radical/B(p-C6F4X)3 Pairs to Give Isolable Bis(borane)superoxide Compounds

Triplet dioxygen was reduced by TEMPO or trityl radicals in the presence of two molar equivalents of the strong B(p-C6F4X)3 (X: F or H) boron Lewis acids under mild conditions to give the bis(borane)superoxide systems 2. T

Reactions of titanium alcoholates Ti(OR)4 (R = n-Bu, t-Bu) with tertiary organic and organometallic hydroperoxides

tert-Butyl and cumyl hydroperoxides in the reactions with Ti(OR) 4 are reduced to alcohols with the evolution of oxygen via formation of titanium-containing peroxides and trioxides. The pathways of the reactions of Ti(OR)4 with triphenylelement hydroperoxides R3EOOH (E = C, Si, Ge) depend on element E and on the structure of R; the reactions involve the rearrangement of the peroxides, and with (n-BuO)4Ti the alkoxy group is oxidized either with preservation or with breakdown of the hydrocarbon skeleton. Pleiades Publishing, Inc., 2006.

Chemiluminescence during thermolysis of the (Ph3COOCPh3)n-Ph3C. peroxide containing captured triphenylmethyl radical

Chemiluminescence (CL) in the thermolysis of (Ph3COOCPh3)n-Ph3C. containing the triphenylmethyl radical captured during the synthesis of Gomberg's peroxide was found. Two CL emitters were identified: the triplet state of benzophenone (3Ph2CO*) and Ph3C.*. Ph3C.* is formed due to the energy transfer from the excited 3Ph2CO* generated in the disproportion of thermolysis intermediates, Ph3CO. radicals. This Ph3C.* luminescence is the first example of CL activation by an organic radical. Chemiluminescence during the thermolysis of Ph3COOCPh3 containing no Ph3C. is resulted from the emission of one emitter, 3Ph2CO*. The solid-phase CL was found during the oxidation of Ph3C. with dioxygen after the destruction of the crystalline lattice as a result of the thermolysis of the (Ph3COOCPh3)n-Ph3C. peroxide.