Phosphoramidic acid, [[(4-methoxyphenyl)amino]thioxomethyl]-, bis(1-methylethyl) ester

Base Information

Chemical Name:Phosphoramidic acid, [[(4-methoxyphenyl)amino]thioxomethyl]-, bis(1-methylethyl) ester
CAS No.:902146-65-0
Molecular Formula:C₁₄H₂₃N₂O₄PS
Molecular Weight:346.387
Hs Code.:

Synonyms:

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Chemical Property of Phosphoramidic acid, [[(4-methoxyphenyl)amino]thioxomethyl]-, bis(1-methylethyl) ester

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of Phosphoramidic acid, [[(4-methoxyphenyl)amino]thioxomethyl]-, bis(1-methylethyl) ester

There total 1 articles about Phosphoramidic acid, [[(4-methoxyphenyl)amino]thioxomethyl]-, bis(1-methylethyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 20177-33-7
diisopropoxyphosphoryl isothiocyanate

: 104-94-9
4-methoxy-aniline

: 902146-65-0
N-(diisopropoxyphosphoryl)-N'-(p-methoxyphenyl)thiocarbamide

Guidance literature:: In dichloromethane; for 0.5h;
DOI:10.1007/s11176-006-0014-2

Reference yield: 84.0%

: 902146-65-0
N-(diisopropoxyphosphoryl)-N'-(p-methoxyphenyl)thiocarbamide

: nickel(II) nitrate hexahydrate

: 953031-44-2
trans-1,3-N,S-[Ni((p-MeOC₆H₄)-N(H)-C(S)-N-P(O)(OiPr)2)2]

Guidance literature:: With KOH; In ethanol; water; a suspn. of a ligand (5 mmol) in aq. ethanol was mixed with an ethanol soln. of KOH (5 mmol); an aq. soln. of Ni-contg. compd. (2.8 mmol) was added dropwise under stirring; the mixt. was stirred at room temp. for a further 5 h and left overnight; the complex was extd. with CH2Cl2, washed with water and dried with anhyd. MgSO4; the solvent was removed in vac.; a ppt. was isolated from CH2Cl2 by n-hexane; elem. anal.;
DOI:10.1039/b702896b

Reference yield: 74.0%

: 902146-65-0
N-(diisopropoxyphosphoryl)-N'-(p-methoxyphenyl)thiocarbamide

: 7646-85-7,24359-56-6
zinc(II) chloride

: 902146-72-9
bis[N-(diisopropoxyphosphoryl)-N'-(p-methoxyphenyl)thiocarbamido-O,S]zinc(II)

Guidance literature:: With potassium hydroxide; In ethanol; water; treatment of soln. of N-(diisopropoxyphosphoryl)-N'-(p-methoxyphenyl)thiocarbamide in EtOH with soln. of KOH in EtOH; stirring for 30 min; addn.dropwise of soln. of ZnCl2 in water (50% excess); stirring for 3-4 h; extn. with small portions of CH2Cl2; drying of combined soln. over MgSO4; removal of solvent; crystn from 1:5 CH2Cl2-hexane mixt.; elem. anal.;
DOI:10.1007/s11176-006-0014-2