1-Menthene

Base Information

• Chemical Name: 1-Menthene
• CAS No.: 15582-48-6
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• DSSTox Substance ID: DTXSID60911567
• Nikkaji Number: J797.763H
• Wikidata: Q82881711
• Mol file: 15582-48-6.mol

Synonyms:1-menthene;o-menthene

Chemical Property of 1-Menthene

Chemical Property:

• Boiling Point: 172.1°Cat760mmHg
• Flash Point: 44.8°C
• PSA: 0.00000
• Density: 0.823g/cm³
• LogP: 3.53290
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 138.140850574
• Heavy Atom Count: 10
• Complexity: 140

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(CCCC1)C(C)C

Technology Process of 1-Menthene

There total 19 articles about 1-Menthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methyl-2-(prop-1-en-2-yl)benzene (7399-49-7) → 2-methylisopropylbenzene (527-84-4) + o-1,4-menthadiene (60264-83-7) + o-3,6-menthadiene (60264-85-9) + o-1-menthene (15582-48-6)

Guidance literature:

With hydrogen; calcium hexammine; In hexane; for 2h; Further byproducts given;

Reference yield:

1-methyl-2-(prop-1-en-2-yl)benzene (7399-49-7) → 2-methylisopropylbenzene (527-84-4) + o-6-menthene (15582-50-0) + o-1-menthene (15582-48-6) + o-2-menthene (15582-49-7)

Guidance literature:

With hydrogen; calcium hexammine; for 24h; Further byproducts given;

Reference yield:

1-methyl-2-(prop-1-en-2-yl)benzene (7399-49-7) → 2-methylisopropylbenzene (527-84-4) + o-1,4-menthadiene (60264-83-7) + o-3,6-menthadiene (60264-85-9) + o-1-menthene (15582-48-6) + o-2-menthene (15582-49-7) + toluene (108-88-3,15644-74-3,16713-13-6)

Guidance literature:

With hydrogen; calcium hexammine; In hexane; for 2h; Product distribution; other mole ratio of hydrogen, other reaction time, other solvent;

upstream raw materials:

1-methyl-2-isopropyl-cyclohexanol-⁽²⁾

1-methyl-2-(prop-1-en-2-yl)benzene

2-methylisopropylbenzene

o-1,4-menthadiene

Downstream raw materials:

o-2-menthene

2-isopropylidene-1-methylcyclohexane

o-6-menthene

Refernces

• 1、 Bazyl'chik, V. V.,Fedorov, P. I.,Odinokov, V. N.. "A NEW FORM OF THE REDUCTION OF BENZENE AND ITS ALKYL-SUBSTITUTRD DERIVATIVES TO 1,4-DIHYDRO DERIVATIVES IN THE LITHIUM-ISOPROPYL ALCOHOL-ETHYLENEDIAMINE SYSTEM". . p. 1668 - 1670. Retrieved 2007/10/02.
• 2、 Bazyl'chik, V. V.. "INVESTIGATION OF COMPOUNDS OF THE MENTHANE SERIES. XVI. REDUCTION OF o- AND p-ISOPROPENYLTOLUENES WITH CALCIUM HEXAAMMONIATE". . p. 1847 - 1851. Retrieved 2007/10/02.