15582-49-7

Basic information

• Product Name: Cyclohexene, 6-methyl-1-(1-methylethyl)-
• CAS NO: 15582-49-7
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• Mol File: 15582-49-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 6-methyl-1-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 6-methyl-1-(1-methylethyl)-(15582-49-7)
• EPA Substance Registry System: Cyclohexene, 6-methyl-1-(1-methylethyl)-(15582-49-7)

Safety Data

• Hazardous Substances Data: 15582-49-7(Hazardous Substances Data)

Upstream product

• 7399-49-7 1-methyl-2-(prop-1-en-2-yl)benzene 
• 527-84-4 2-methylisopropylbenzene 
• 60264-83-7 o-1,4-menthadiene 
• 15582-48-6 o-1-menthene 
• 180092-32-4 [2-(1-methylethenyl)phenyl]methyl alcohol 
• 7073-70-3 1-bromo-2-isopropenylbenzene 
• 3609-45-8 1-chloro-2-(prop-1-en-2-yl)benzene 
• 6091-64-1 2-bromobenzoic acid ethyl ester 
• 7073-69-0 2-(2-bromophenyl)propanol 
• 7335-25-3 ethyl 2-chlorobenzoate 
• 21190-34-1 (2-isopropylphenyl)methanol 
• 3670-15-3 2-(2-chlorophenyl)propan-2-ol 
• 583-60-8 2-Methylcyclohexanone 
• 6129-90-4 1-methyl-2-isopropyl-cyclohexanol-⁽²⁾ 

Relevant articles and documents

Compounds of the menthane series. Synthesis of unsaturated primary alcohols with the o- and p-menthane skeletons

Precursors to terpene alcohols of the o- and p-menthane series (o-cimen-7-ol and o- and p-cimen-9-ols) were synthesized, and their reduction with lithium in ethylenediamine was studied. The reduction of o- and p-cimen-9-ols in the presence of isopropyl alcohol selectively afforded the corresponding 1,4-dihydro derivatives. Under analogous conditions, o-cimen-7-ol was converted into a mixture of unsaturated hydrocarbons. The reduction with lithium in ethylenediamine in the absence of isopropyl alcohol in all cases gave mixtures of menthene alcohols.

A NEW FORM OF THE REDUCTION OF BENZENE AND ITS ALKYL-SUBSTITUTRD DERIVATIVES TO 1,4-DIHYDRO DERIVATIVES IN THE LITHIUM-ISOPROPYL ALCOHOL-ETHYLENEDIAMINE SYSTEM

A new method, convenient and effective for preparative purposes, is proposed for the reduction of benzene, toluene, and o-cymene in the lithium-isopropyl alcohol-ethylenediamine system.It is based on reaction at 85-95 deg C with arene, alcohol, diamine, and metal in molar equivalent ratios of 1:4-6:0.25-0.5:2-3.

INVESTIGATION OF COMPOUNDS IN THE o-MENTHANE SERIES XI. ISOMERIZATION TRANSFORMATIONS OF o-1,4-MENTHADIENES

Under the conditions of base catalysis under the influence of potassium tert-butoxide in dimethyl sulfoxide and lithium and calcium amides o-1,4-menthadiene forms equilibrium mixtures of o-1,3-menthadiene, o-1,5-menthadiene, and the skeletal rearrangement product 1-isopropyl-5-ethylidenecyclopentene.In the presence of NaX and KX zeolites competing dehydrogenation and disproportionation of the hydrogen occur in o-1,4-menthadiene with the formation of a mixture of o-menthenes and o-cymene.With increase in temperature the dehydration process becomes determining.With acid catalysis the transformation of o-1,4-menthadiene into 1-isopropyl-5-ethylidenecyclopentene and dehydration to o-cymene are the mainpaths.