Rhodium,triamminetrichloro-, (OC-6-21)-

Base Information

• Chemical Name: Rhodium,triamminetrichloro-, (OC-6-21)-
• CAS No.: 26566-81-4
• Molecular Formula: Cl₃H₉N₃Rh
• Molecular Weight: 260.356
• Mol file: 26566-81-4.mol

Synonyms:Rhodium,triamminetrichloro-, trans- (8CI); NSC 153153; fac-Triamminetrichlororhodium

Chemical Property of Rhodium,triamminetrichloro-, (OC-6-21)-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Rhodium,triamminetrichloro-, (OC-6-21)-

There total 3 articles about Rhodium,triamminetrichloro-, (OC-6-21)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

rhodium(III) trichloride hydrate + ammonia (7664-41-7) → triamminetrichlororhodium (26566-81-4,21264-82-4,26566-80-3) + chloropentaamminerhodium(III) chloride + {Rh(NH3)4Cl2}(1+)*Cl(1-)={Rh(NH3)4Cl2}Cl (71382-19-9,21288-85-7,37488-14-5)

Guidance literature:

rhodium(III) trichloride hydrate; With hydrogenchloride; In water; for 0.5h; Heating;

ammonia; pH=8.2; Heating;

DOI:10.1002/ejic.201900488

Reference yield: 70.0%

ammonium acetate (92206-38-7) + sodium hexachlororhodate(III) dodecahydrate + ammonium chloride → triamminetrichlororhodium (26566-81-4,21264-82-4,26566-80-3)

Guidance literature:

With acetic acid; In water; aq. soln. of Na3(RhCl6) and ammonium chloride were heated nearly to boiling; addn. of ammonium acetate and acetic acid; further heating leads to discoloration; pptn.;;

Reference yield:

[Rh(NH3)3(OH)3] (26566-79-0) → triamminetrichlororhodium (26566-81-4,21264-82-4,26566-80-3)

Guidance literature:

With hydrogenchloride;

DOI:10.1016/0022-5088(69)90166-0

upstream raw materials:

ammonium acetate

[Rh(NH₃)3(OH)3]

ammonia

Refernces