3,9-Dioxa-5,7-dithia-4,8-diphospha-6-stannaundecane, 6-[(diethoxyphosphinothioyl)thio]-4,8-diethoxy-6-phenyl-, 4,8-disulfide

Base Information

• Chemical Name: 3,9-Dioxa-5,7-dithia-4,8-diphospha-6-stannaundecane, 6-[(diethoxyphosphinothioyl)thio]-4,8-diethoxy-6-phenyl-, 4,8-disulfide
• CAS No.: 90813-35-7
• Molecular Formula: C₁₈H₃₅O₆P₃S₆Sn
• Molecular Weight: 751.5
• Mol file: 90813-35-7.mol

Synonyms:

Chemical Property of 3,9-Dioxa-5,7-dithia-4,8-diphospha-6-stannaundecane, 6-[(diethoxyphosphinothioyl)thio]-4,8-diethoxy-6-phenyl-, 4,8-disulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,9-Dioxa-5,7-dithia-4,8-diphospha-6-stannaundecane, 6-[(diethoxyphosphinothioyl)thio]-4,8-diethoxy-6-phenyl-, 4,8-disulfide

There total 1 articles about 3,9-Dioxa-5,7-dithia-4,8-diphospha-6-stannaundecane, 6-[(diethoxyphosphinothioyl)thio]-4,8-diethoxy-6-phenyl-, 4,8-disulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium O,O-diethyl phosphorodithioate (3338-24-7) + phenyltin trichloride (1124-19-2) → C6H5Sn(S2P(OC2H5)2)3 (90813-35-7)

Guidance literature:

In dichloromethane; byproducts: NaCl; react. of the PhSnCl3 with the appropriate mole ratio of the diethyldithiophosphate; filtration, evapn., isolation only as an oil;

DOI:10.1016/S0020-1693(00)85595-4

Reference yield:

C6H5Sn(S2COC2H5)3 + C6H5Sn(S2P(OC2H5)2)3 (90813-35-7) → C6H5(1-)*Sn(4+)*2S2P(OC2H5)2(1-)*S2C(OC2H5)(1-)=C6H5Sn(S2P(OC2H5)2)2(S2C(OC2H5)) + C6H5(1-)*Sn(4+)*2S2C(OC2H5)(1-)*S2P(OC2H5)2(1-)=C6H5Sn(S2C(OC2H5))2(S2P(OC2H5)2)

Guidance literature:

In dichloromethane; not isolated, detn. by (119)Sn NMR;

DOI:10.1016/S0020-1693(00)85595-4

Reference yield:

C6H5Sn(SSCN(C2H5)2)3 (1104253-33-9) + C6H5Sn(S2P(OC2H5)2)3 (90813-35-7) → C6H5(1-)*Sn(4+)*2S2P(OC2H5)2(1-)*S2CN(C2H5)2(1-)=C6H5Sn(S2P(OC2H5)2)2(S2CN(C2H5)2) + phenyltin(IV) (diethyldithiocarbamate)2(diethyldithiophosphate)

Guidance literature:

In dichloromethane; not isolated, detn. by (119)Sn NMR;

DOI:10.1016/S0020-1693(00)85595-4

upstream raw materials:

sodium O,O-diethyl phosphorodithioate

phenyltin trichloride