10-Chlorophenoxarsine

Base Information

• Chemical Name: 10-Chlorophenoxarsine
• CAS No.: 2865-70-5
• Molecular Formula: C12H8 As Cl O
• Molecular Weight: 278.57
• Hs Code.: 2934999090
• European Community (EC) Number: 220-684-6
• NSC Number: 16081
• DSSTox Substance ID: DTXSID6062674
• Nikkaji Number: J13.731F
• Wikidata: Q81990184
• Mol file: 2865-70-5.mol

Synonyms:10-Chlorophenoxarsine;10-Chloro-10H-phenoxarsine;DID 95;10H-Phenoxarsine, 10-chloro-;PHENOXARSINE, 10-CHLORO-;2865-70-5;EINECS 220-684-6;NSC 16081;BRN 0178697;2-27-00-00947 (Beilstein Handbook Reference);C12H8AsClO;C12-H8-As-Cl-O;DID-95;SCHEMBL8821946;10-Chloro-10H-phenoxarsine #;DTXSID6062674;NSC16081;NSC-16081;WLN: T C666 B-AS- IOJ BG;LS-105700

Chemical Property of 10-Chlorophenoxarsine

Chemical Property:

• Vapor Pressure: 3.38E-05mmHg at 25°C
• Melting Point: 122°C
• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 174.8°C
• PSA: 9.23000
• Density: g/cm³
• LogP: 2.13680
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 277.947962
• Heavy Atom Count: 15
• Complexity: 214

Purity/Quality:

99% ^*data from raw suppliers

10-CHLORO-10H-PHENOXARSINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)OC3=CC=CC=C3[As]2Cl

Technology Process of 10-Chlorophenoxarsine

There total 7 articles about 10-Chlorophenoxarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.4%

o,o'-bis(dichloroarseno)diphenyl oxide (139888-60-1) → 10-chloro-10H-phenoxarsine (2865-70-5)

Guidance literature:

at 200 - 220 ℃; for 2h; under 12 Torr;

Reference yield: 57.2%

diphenylether (101-84-8) → 10-chloro-10H-phenoxarsine (2865-70-5) + o,o'-bis(dichloroarseno)diphenyl oxide (139888-60-1)

Guidance literature:

With aluminium trichloride; sulfuric acid; arsenic trichloride; Heating;

Reference yield:

diphenylether (101-84-8) → 10-chloro-10H-phenoxarsine (2865-70-5)

Guidance literature:

With aluminium trichloride; arsenic trichloride; at 200 ℃;

upstream raw materials:

diphenylether

dichloro-(2-phenoxy-phenyl)-arsine

o,o'-bis(dichloroarseno)diphenyl oxide

(2-phenoxy-phenyl)-arsonic acid

Downstream raw materials:

10-iodophenoxarsine

10,10,oxybisphenoxarsine

10-cyclohexyl-10H-phenoxarsine

10-benzyl-10H-phenoxarsine

Refernces

• 1、 Gavrilov, V. I.,Pilishkina, L. M.,Khalitov, F. G.. "ARSENATION OF DIPHENYL OXIDE WITH ARSENIC TRICHLORIDE". . p. 2055 - 2057. Retrieved 2007/10/02.