(Z)-4-Nitro-alpha-(p-nitrophenyl)cinnamic acid

Base Information

• Chemical Name: (Z)-4-Nitro-alpha-(p-nitrophenyl)cinnamic acid
• CAS No.: 6277-62-9
• Molecular Formula: C15H10N2O6
• Molecular Weight: 314.254
• NSC Number: 34874
• Mol file: 6277-62-9.mol

Synonyms:NSC34874;(Z)-4-Nitro-alpha-(p-nitrophenyl)cinnamic acid;6277-62-9;NSC-34874;(2E)-2,3-Bis(4-nitrophenyl)-2-propenoic acid #

Chemical Property of (Z)-4-Nitro-alpha-(p-nitrophenyl)cinnamic acid

Chemical Property:

• Vapor Pressure: 2.05E-08mmHg at 25°C
• Boiling Point: 437.2°Cat760mmHg
• Flash Point: 179.6°C
• Density: 1.49g/cm³
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 314.05388604
• Heavy Atom Count: 23
• Complexity: 491

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C=C(C2=CC=C(C=C2)[N+](=O)[O-])C(=O)O)[N+](=O)[O-]
• Isomeric SMILES: C1=CC(=CC=C1/C=C(\C2=CC=C(C=C2)[N+](=O)[O-])/C(=O)O)[N+](=O)[O-]

Technology Process of (Z)-4-Nitro-alpha-(p-nitrophenyl)cinnamic acid

There total 10 articles about (Z)-4-Nitro-alpha-(p-nitrophenyl)cinnamic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitrobenzeneacetic acid (104-03-0) + 4-nitrobenzaldehdye (555-16-8) → 2,3t-bis-(4-nitro-phenyl)-acrylic acid (6277-62-9)

Guidance literature:

With tri-n-propylamine; acetic anhydride;

DOI:10.1021/ja01154a509

Reference yield:

4-nitrobenzaldehdye (555-16-8) → 2,3t-bis-(4-nitro-phenyl)-acrylic acid (6277-62-9)

Guidance literature:

With acetic anhydride; zinc(II) chloride;

DOI:10.1002/hlca.19380210107

Reference yield:

(E)-2,3-diphenylpropenoic acid (91-48-5) → 2,3t-bis-(4-nitro-phenyl)-acrylic acid (6277-62-9)

Guidance literature:

With sulfuric acid; nitric acid;

upstream raw materials:

2,3-bis-(4-nitro-phenyl)-acrylic acid ethyl ester

ETHYL 4-NITROPHENYLACETATE

4-nitrobenzaldehdye

(E)-2,3-diphenylpropenoic acid

Downstream raw materials:

(Z)-4,4'-dinitrostilbene

2,3t-bis-(4-nitro-phenyl)-acrylic acid ethyl ester

trans-4,4'-dinitrostilbene

2,3t-bis-(4-nitro-phenyl)-acrylic acid methyl ester