1,1,1-Trimethylolpropane polyglycidyl ether

Base Information

• Chemical Name: 1,1,1-Trimethylolpropane polyglycidyl ether
• CAS No.: 42765-17-3
• Molecular Formula: C15H26O6
• Molecular Weight: 302.368
• Mol file: 42765-17-3.mol

Synonyms:1,1,1-Trimethylolpropane polyglycidyl ether

Chemical Property of 1,1,1-Trimethylolpropane polyglycidyl ether

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1,1,1-Trimethylolpropane polyglycidyl ether

There total 4 articles about 1,1,1-Trimethylolpropane polyglycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

trimethylolpropane triallyl ether (682-08-6) → 1,1,1-trimethylolpropane triglycidyl ether (3454-29-3,42765-17-3)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; at 20 ℃; for 72h;

Reference yield: 76.0%

1,1,1-tri(hydroxymethyl)propane (77-99-6) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → 1,1,1-trimethylolpropane triglycidyl ether (3454-29-3,42765-17-3)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 30 ℃; for 7h;

DOI:10.1055/s-1993-25890

Reference yield:

1,1,1-tri(hydroxymethyl)propane (77-99-6) → 1,1,1-trimethylolpropane triglycidyl ether (3454-29-3,42765-17-3)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide; tetrabutylammomium bromide / tetrahydrofuran / 24 h / 70 °C

2: 3-chloro-benzenecarboperoxoic acid / chloroform / 72 h / 20 °C

With tetrabutylammomium bromide; 3-chloro-benzenecarboperoxoic acid; potassium hydroxide; In tetrahydrofuran; chloroform;

upstream raw materials:

1,1,1-tri(hydroxymethyl)propane

epichlorohydrin

trimethylolpropane triallyl ether

Refernces

• 1、 -. "METHOD FOR PRODUCING EPOXY COMPOUND BY OXIDATION". Paragraph 0038. . Retrieved 2013/06/27.
• 2、 -. "Amid group-containing diisocyanates and amide group-containing epoxy resins". . . Retrieved 2008/06/13.