1-(Allyloxy)-2,2-bis((allyloxy)methyl)butane

Base Information

• Chemical Name: 1-(Allyloxy)-2,2-bis((allyloxy)methyl)butane
• CAS No.: 682-08-6
• Molecular Formula: C15H26 O3
• Molecular Weight: 254.37
• Hs Code.: 2909199090
• European Community (EC) Number: 211-660-6
• DSSTox Substance ID: DTXSID0060987
• Nikkaji Number: J205.986J
• Wikidata: Q81989256
• Mol file: 682-08-6.mol

Synonyms:682-08-6;1-(Allyloxy)-2,2-bis((allyloxy)methyl)butane;1-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)butane;1-(ALLYLOXY)-2,2-BIS[(ALLYLOXY)METHYL]BUTANE;EINECS 211-660-6;1,1,1-Trimethylolpropane triallyl ether;Butane, 2,2-di((2-propenyloxy)methyl)-1-(2-propenyloxy)-;Butane,1-(2-propen-1-yloxy)-2,2-bis[(2-propen-1-yloxy)methyl]-;Butane, 1-(2-propenyloxy)-2,2-bis((2-propenyloxy)methyl)-;Butane, 1-(2-propenyloxy)-2,2-bis[(2-propenyloxy)methyl]-;Butane, 1-(2-propen-1-yloxy)-2,2-bis((2-propen-1-yloxy)methyl)-;SCHEMBL160932;DTXSID0060987;AKOS025296125;1,1,1-Tris[(2-propenyloxy)methyl]propane

Chemical Property of 1-(Allyloxy)-2,2-bis((allyloxy)methyl)butane

Chemical Property:

• Vapor Pressure: 0.00151mmHg at 25°C
• Boiling Point: 305.1°C at 760 mmHg
• Flash Point: 115.3°C
• PSA: 27.69000
• Density: 0.906g/cm³
• LogP: 2.99060
• XLogP3: 2.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 13
• Exact Mass: 254.18819469
• Heavy Atom Count: 18
• Complexity: 200

Purity/Quality:

99% ^*data from raw suppliers

1-(ALLYLOXY)-2,2-BIS[(ALLYLOXY)METHYL]BUTANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(COCC=C)(COCC=C)COCC=C

Technology Process of 1-(Allyloxy)-2,2-bis((allyloxy)methyl)butane

There total 2 articles about 1-(Allyloxy)-2,2-bis((allyloxy)methyl)butane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,1,1-tri(hydroxymethyl)propane (77-99-6) + 3-chloroprop-1-ene (107-05-1) → trimethylolpropane triallyl ether (682-08-6)

Guidance literature:

With sodium hydroxide; sodium chloride; tetrabutylammomium bromide; In toluene;

Reference yield: 90.0%

1,1,1-tri(hydroxymethyl)propane (77-99-6) + allyl bromide (106-95-6) → trimethylolpropane triallyl ether (682-08-6)

Guidance literature:

With tetrabutylammomium bromide; potassium hydroxide; In tetrahydrofuran; at 70 ℃; for 24h;

Reference yield: 91.0%

trimethylolpropane triallyl ether (682-08-6) → 1,1,1-trimethylolpropane triglycidyl ether (3454-29-3,42765-17-3)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; at 20 ℃; for 72h;

upstream raw materials:

1,1,1-tri(hydroxymethyl)propane

3-chloroprop-1-ene

allyl bromide

Downstream raw materials:

1,1,1-trimethylolpropane triglycidyl ether

Refernces

• 1、 Baranek, Austin,Song, Han Byul,McBride, Mathew,Finnegan, Patricia,Bowman, Christopher N.. "Thermomechanical Formation-Structure-Property Relationships in Photopolymerized Copper-Catalyzed Azide-Alkyne (CuAAC) Networks". . p. 1191 - 1200. Retrieved 2016/03/25.
• 2、 Lee, Haejoo,Ooya, Tooru. "Dendritic nanospace constructed by only glycerol units enhanced uptake of a fluorescent molecule in aqueous solution". supporting information; experimental part. p. 546 - 548. Retrieved 2012/02/05.