7-[(Benzyloxy)methyl]-3,6,9,12-tetraoxatetradecane-1,14-diol

Base Information

Chemical Name:7-[(Benzyloxy)methyl]-3,6,9,12-tetraoxatetradecane-1,14-diol
CAS No.:91472-18-3
Molecular Formula:C18H30O7
Molecular Weight:358.432
Hs Code.:
DSSTox Substance ID:DTXSID50524120

Synonyms:91472-18-3;DTXSID50524120;7-[(BENZYLOXY)METHYL]-3,6,9,12-TETRAOXATETRADECANE-1,14-DIOL

Suppliers and Price of 7-[(Benzyloxy)methyl]-3,6,9,12-tetraoxatetradecane-1,14-diol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 7-[(Benzyloxy)methyl]-3,6,9,12-tetraoxatetradecane-1,14-diol

Chemical Property:

PSA：86.61000
LogP:0.62280
XLogP3:-0.3
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:17
Exact Mass:358.19915329
Heavy Atom Count:25
Complexity:272

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)COCC(COCCOCCO)OCCOCCO

Technology Process of 7-[(Benzyloxy)methyl]-3,6,9,12-tetraoxatetradecane-1,14-diol

There total 4 articles about 7-[(Benzyloxy)methyl]-3,6,9,12-tetraoxatetradecane-1,14-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 94650-69-8
1,14-Bis-7-benzyloxymethyl-3,6,9,12-tetraoxatetradecane

: 91472-18-3
7-<(benzyloxy)methyl>-3,6,9,12-tetraoxa-1,14-tetradecanediol

Guidance literature:: With hydrogenchloride; In methanol; dichloromethane; for 2h; Ambient temperature;
DOI:10.1055/s-1984-30970

Reference yield:

: 13071-59-5,17325-85-8,56552-80-8,4799-67-1
3-benzyloxypropan-1,2-diol

: 91472-18-3
7-<(benzyloxy)methyl>-3,6,9,12-tetraoxa-1,14-tetradecanediol

Guidance literature:: Multi-step reaction with 4 steps

1: 50percent aq. sodium hydroxide / tetrabutylammonium hydrogen sulfate / 72 h / 65 °C

2: aq. HCl / methanol; CH₂Cl₂ / 2 h / Ambient temperature

3: 50percent aq. sodium hydroxide / tetrabutylammonium hydrogen sulfate / 72 h / 65 °C

4: aq. HCl / methanol; CH₂Cl₂ / 2 h / Ambient temperature

With hydrogenchloride; sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In methanol; dichloromethane;
DOI:10.1021/jo00265a026

Reference yield:

: 80525-60-6,118917-64-9
4-Benzyloxymethyl-3,6-dioxa-1,8-octanediol

: 91472-18-3
7-<(benzyloxy)methyl>-3,6,9,12-tetraoxa-1,14-tetradecanediol

Guidance literature:: Multi-step reaction with 2 steps

1: 50percent aq. sodium hydroxide / tetrabutylammonium hydrogen sulfate / 72 h / 65 °C

2: aq. HCl / methanol; CH₂Cl₂ / 2 h / Ambient temperature

With hydrogenchloride; sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In methanol; dichloromethane;
DOI:10.1021/jo00265a026