benzene,cobalt,N-[(Z)-1-methyl-2-nitroso-prop-1-enyl]hydroxylamine,pyridine

Base Information

Chemical Name:benzene,cobalt,N-[(Z)-1-methyl-2-nitroso-prop-1-enyl]hydroxylamine,pyridine
CAS No.:29130-85-6
Molecular Formula:C₁₉H₂₄CoN₅O₄
Molecular Weight:445.424
Hs Code.:
Mol file:29130-85-6.mol

Synonyms:Cobalt,bis(2,3-butanedione dioximato)phenyl(pyridine)-, trans- (8CI); Cobalt,bis(dimethylglyoximato)phenyl(pyridine)- (7CI); Cobalt, bis[(2,3-butanedionedioximato)(1-)-N,N']phenyl(pyridine)-, (OC-6-12)-; 2,3-Butanedione, dioxime,cobalt complex; NSC 169945

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzene,cobalt,N-[(Z)-1-methyl-2-nitroso-prop-1-enyl]hydroxylamine,pyridine

Chemical Property:

Vapor Pressure:0.134mmHg at 25°C
Boiling Point:192°Cat760mmHg
Flash Point:69.9°C
Density:g/cm³

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of benzene,cobalt,N-[(Z)-1-methyl-2-nitroso-prop-1-enyl]hydroxylamine,pyridine

There total 5 articles about benzene,cobalt,N-[(Z)-1-methyl-2-nitroso-prop-1-enyl]hydroxylamine,pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: chloropyridinecobaloxime(III)

: 100-58-3
phenylmagnesium bromide

: 29130-85-6
phenylcobaloxime

Guidance literature:: In tetrahydrofuran; soln. of Mg compd. in THF was added dropwise to stirred cold suspn. of Co complex in THF under N2; stirred for 2 h; refluxed for 0.5 h; quenched with cold aq. HCl; filtered; petroleum ether added; filtered; residue combined; washed (EtOH, petroleum ether, H2O); dried (vac., P2O5); chromd. (silica gel, 20% EtOAc/CHCl3); elem. anal.;
DOI:10.1016/j.jorganchem.2010.06.012

Reference yield: 46.0%

: triphenylstannylcobaloxime

: 5582-60-5
4-(methoxymethyloxy)but-1-yne

: 329200-83-1
(C₆H₅)3SnCCCH₂CH₂OCH₂OCH₃

: 29130-85-6
phenylcobaloxime

Guidance literature:: In acetonitrile; Irradiation (UV/VIS); mixt. of Co complex and enyne in acetonitrile, which was deaerated in ultrasonic bath with bubbling argon, was refluxed for 19 h under argon; condensed in vac.; residue was pass through column of Florisil (CH2Cl2);eluate was subjected to TLC sepn. (hexane-ethyl acetate, 10/1);
DOI:10.1016/S0022-328X(00)00550-7

Reference yield: 36.0%

: triphenylstannylcobaloxime

: 75405-45-7
4-(prop-2-en-1-yloxy)but-1-yne

: 329200-84-2
(C₆H₅)3SnCCCH₂CH₂OCH₂CHCH₂

: 29130-85-6
phenylcobaloxime

Guidance literature:: In acetonitrile; Irradiation (UV/VIS); mixt. of Co complex and enyne in acetonitrile, which was deaerated in ultrasonic bath with bubbling argon, was refluxed for 18 h under argon; condensed in vac.; residue was pass through column of Florisil (CH2Cl2);eluate was subjected to TLC sepn. (hexane-ethyl acetate, 10/1);
DOI:10.1016/S0022-328X(00)00550-7