2,3-Anthracenedicarboxaldehyde

Base Information

• Chemical Name: 2,3-Anthracenedicarboxaldehyde
• CAS No.: 76197-35-8
• Molecular Formula: C16H10O2
• Molecular Weight: 234.25
• Hs Code.: 2912299000
• European Community (EC) Number: 622-099-5
• DSSTox Substance ID: DTXSID60227054
• Nikkaji Number: J354.011A
• Wikidata: Q27122533
• Metabolomics Workbench ID: 57687
• Mol file: 76197-35-8.mol

Synonyms:2,3-ADA;2,3-anthracenedicarboxaldehyde;anthracene-2,3-dialdehyde

Chemical Property of 2,3-Anthracenedicarboxaldehyde

Chemical Property:

• Vapor Pressure: 2.87E-09mmHg at 25°C
• Melting Point: 220 °C (sublm)(Press: 0.1 Torr)
• Refractive Index: 1.773
• Boiling Point: 477.1 °C at 760 mmHg
• Flash Point: 177.1 °C
• PSA: 34.14000
• Density: 1.294 g/cm³
• LogP: 3.61800
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 234.068079557
• Heavy Atom Count: 18
• Complexity: 293

Purity/Quality:

98%Min ^*data from raw suppliers

ANTHRACENE-2,3-DICARBOXALDEHYDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C2C=C3C=C(C(=CC3=CC2=C1)C=O)C=O

Technology Process of 2,3-Anthracenedicarboxaldehyde

There total 9 articles about 2,3-Anthracenedicarboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(3-hydroxymethyl-anthracen-2-yl)-methanol (1134642-63-9) → anthracene-2,3 dicarboxaldehyde (76197-35-8)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; dimethyl sulfoxide; at 0 - 5 ℃; for 1h;

DOI:10.1039/d0cc06620f

Reference yield: 20.0%

cis,trans-2,5-dimethoxytetrahydrofuran (696-59-3) + o-phthalic dicarboxaldehyde (643-79-8) → anthracene-2,3 dicarboxaldehyde (76197-35-8)

Guidance literature:

With piperidine; acetic acid; In water; for 24h; Heating;

DOI:10.1055/s-1980-29170

Reference yield: 7.0%

cis,trans-2,5-dimethoxytetrahydrofuran (696-59-3) + o-phthalic dicarboxaldehyde (643-79-8) → 2,3-naphthalenedicarboxaldehyde (7149-49-7) + anthracene-2,3 dicarboxaldehyde (76197-35-8)

Guidance literature:

With piperidine; acetic acid; In water; for 15h; Heating;

DOI:10.1055/s-1980-29170

upstream raw materials:

cis,trans-2,5-dimethoxytetrahydrofuran

o-phthalic dicarboxaldehyde

2,3-naphthalenedicarboxaldehyde

(3-hydroxymethyl-anthracen-2-yl)-methanol

Refernces

• 1、 Zhang, Kui,Cai, Lingchao,Jiang, Xing,Garcia-Garibay, Miguel A.,Kwon, Ohyun. "Phosphine-Mediated Iterative Arene Homologation Using Allenes". . p. 11258 - 11261. Retrieved 2015/09/21.
• 2、 Ishibashi, Kenichi,Iyoda, Tomokazu,Hashimoto, Kazuhito,Fujishima, Akira,Shirai, Yasuo,Jiro, Abe. "First-order hyperpolarizability of oligo-acene derivatives by hyper-Rayleigh scattering". . p. 107 - 111. Retrieved 2007/10/03.