LITHIUM THIOCYANATE

Base Information

• Chemical Name: LITHIUM THIOCYANATE
• CAS No.: 556-65-0
• Molecular Formula: CNS•Li
• Molecular Weight: 65.0247
• Mol file: 556-65-0.mol

Synonyms:Thiocyansaeure,Lithiumthiocyanat;AR-1J3270;Lithiumrhodanid;lithium rhodanide;thiocyanic acid,lithium thiocyanate;EINECS 209-135-1;Li(thiocyanate);Thiocyanic acid,lithium salt (1:1);Lithium thiocyanate;Thiocyanic acid,lithium salt;CTK5A3959;Lithium sulfocyanate;Thiocyanic acid, lithium salt;

Chemical Property of LITHIUM THIOCYANATE

Chemical Property:

• Vapor Pressure: 4.73mmHg at 25°C
• Melting Point: 281 °C
• Boiling Point: 146°Cat760mmHg
• Flash Point: 42.1°C
• PSA: 23.79000
• Density: g/cm³
• LogP: 0.01438
• Water Solubility.: g/100g H2O: 12025 [CRC10]

Purity/Quality:

99% ^*data from raw suppliers

Lithium Thiocyanate 99.9% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of LITHIUM THIOCYANATE

There total 23 articles about LITHIUM THIOCYANATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium azidodithiocarbonate monohydrate → lithium thiocyanate (556-65-0)

Guidance literature:

In neat (no solvent); byproducts: N2, S; on dehydration and heating decomposition in LiSCN, N2 and S;;

DOI:10.1021/ja01403a004

Reference yield:

thiocyanic acid (463-56-9) + lithium carbonate (554-13-2) → lithium thiocyanate (556-65-0)

Guidance literature:

In water; neutralization of 18-20% aq. HSCN with Li2CO3;; evaporation of H2O, extraction with alc. and drying over H2SO4 (48 h, 2 Torr);;

Reference yield:

lithium sulfate + barium thiocyanate (2092-17-3) → lithium thiocyanate (556-65-0)

Guidance literature:

In water; under dry argon; solution was filtered, evaporated to dryness in a rotavapor, dried for 48 h in high vacuum (1E-4 Torr) at 90°C;

DOI:10.1039/DT9810000501

upstream raw materials:

thiourea

Downstream raw materials:

allyl thiocyanate

t-1-iodo-c-2-isothiocyanato-r-1-trimethylsilylcyclohexane

Refernces

• 1、 Oshurkova,Nesterov. "Synthesis of new electrolytes in solutions with dc current". . p. 1605 - 1609. Retrieved 2005.
• 2、 Lee, Yi-Chia,Price, David L.,Curtiss, Larry A.,Ratner, Mark A.,Shriver, Duward F.. "Structure of the ambient temperature alkali metal molten salt AlCl3/LiSCN". . p. 4591 - 4594. Retrieved 2001.
• 3、 Solov'ev, V. P.,Strakhova, N. N.,Raevskii, O. A.. "EQUILIBRIUM CONSTANTS AND COMPLEXATION ENTHALPIES AND ENTROPIES OF LITHIUM, SODIUM, POTASSIUM, AMMONIUM, AND CALCIUM THIOCYANATES WITH BENZO-12-CROWN-4 IN ACETONITRILE". . p. 2163 - 2165. Retrieved 2007/10/02.