2,2':6',2''-Terpyridine, 4'-[4-[bis(2,4,6-trimethylphenyl)boryl]phenyl]-

Base Information

• Chemical Name: 2,2':6',2''-Terpyridine, 4'-[4-[bis(2,4,6-trimethylphenyl)boryl]phenyl]-
• CAS No.: 919990-72-0
• Molecular Formula: C39H36BN3
• Molecular Weight: 557.546
• Mol file: 919990-72-0.mol

Synonyms:

Chemical Property of 2,2':6',2''-Terpyridine, 4'-[4-[bis(2,4,6-trimethylphenyl)boryl]phenyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2':6',2''-Terpyridine, 4'-[4-[bis(2,4,6-trimethylphenyl)boryl]phenyl]-

There total 1 articles about 2,2':6',2''-Terpyridine, 4'-[4-[bis(2,4,6-trimethylphenyl)boryl]phenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

1-iodo-4-(dimesitylboryl)-benzene (177595-61-8) + 4'-((neopentyl glycolato)boron)-2,2':6',2''-terpyridine (381218-94-6) → 4'-phenyl(dimesitylboryl)-2,2':6',2''-terpyridine (919990-72-0)

Guidance literature:

With Na₂CO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; ethanol; acetonitrile; (N2); addn. to soln. of iodide deriv. and palladium in THF of soln. of terpyridine deriv. in CH3CN, THF and ethanol (10:15:15), addn. of 2 M aqueous Na2CO3, refluxing at 85°C for 6 h, TLC monitoring; evapn., dissolving in CH2Cl2, washing with water and 0.1 M aqueous NaOH,drying under Na2SO4, evapn., chromy. (deactivated alumina, ethyl acetat e/hexane (1:9)), NMR and MS;

DOI:10.1021/ic061435b

Reference yield: 53.0%

ammonium hexafluorophosphate + dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 4'-phenyl(dimesitylboryl)-2,2':6',2''-terpyridine (919990-72-0) → [Pt(4'-phenyl(dimesitylboryl)-2,2':6',2''-terpyridine)Cl]PF6 (919990-70-8)

Guidance literature:

In methanol; addn. of terpyridine deriv. to suspn. of platinum compd. in methanol, heating at 60°C for 2 h, cooling to room temp., filtration, evapn.,washing with ether, addn. of methanol, addn. of methanolic soln. of NH4 PF6; suction filtration, recrystn. (acetone), elem. anal.;

DOI:10.1021/ic061435b

upstream raw materials:

1-iodo-4-(dimesitylboryl)-benzene

4'-((neopentyl glycolato)boron)-2,2':6',2''-terpyridine

Downstream raw materials:

[Pt(4'-phenyl(dimesitylboryl)-2,2':6',2''-terpyridine)Cl]PF₆