Benzenecarboximidic acid, N-[[(diphenylphosphino)methyl]dimethylsilyl]-, [(diphenylphosphino)methyl]dimethylsilyl ester

Base Information

• Chemical Name: Benzenecarboximidic acid, N-[[(diphenylphosphino)methyl]dimethylsilyl]-, [(diphenylphosphino)methyl]dimethylsilyl ester
• CAS No.: 92097-66-0
• Molecular Formula: C37H41NOP2Si2
• Molecular Weight: 633.857
• Mol file: 92097-66-0.mol

Synonyms:

Chemical Property of Benzenecarboximidic acid, N-[[(diphenylphosphino)methyl]dimethylsilyl]-, [(diphenylphosphino)methyl]dimethylsilyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenecarboximidic acid, N-[[(diphenylphosphino)methyl]dimethylsilyl]-, [(diphenylphosphino)methyl]dimethylsilyl ester

There total 1 articles about Benzenecarboximidic acid, N-[[(diphenylphosphino)methyl]dimethylsilyl]-, [(diphenylphosphino)methyl]dimethylsilyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzoyl chloride (98-88-4) + ((C6H5)2PCH2Si(CH3)2)2N(1-)*Li(1+)=((C6H5)2PCH2Si(CH3)2)2NLi (77617-69-7) → C37H41NOP2Si2 (92097-66-0)

Guidance literature:

In toluene; -78 deg C -> r.t.;

DOI:10.1021/ja00335a022

Reference yield: 60.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + C6H5CN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2 (92097-66-0) → Ni(CO)2{(C6H5)CN(Si(CH3)2CH2P(C6H5)2)OSi(CH3)2CH2P(C6H5)2}

Guidance literature:

With carbon monoxide; In toluene; the ligand in toluene was slowly added at -78°C under inert atmosphere to a toluene soln. of Ni(COD)2, mixt. was stirred at -78°C for 1 h, warmed to 0°C (1 h), allowed to come to room temp., stirred for 1 h under 1 atm of CO; solvent and excess of CO were removed, residue crystd. from hexane;

DOI:10.1021/ja00335a022

upstream raw materials:

benzoyl chloride

((C₆H₅)2PCH₂Si(CH₃)2)2N^(1-)*Li⁽¹⁺⁾=((C₆H₅)2PCH₂Si(CH₃)2)2NLi