Lithium hydroxide monohydrate

Base Information

• Chemical Name: Lithium hydroxide monohydrate
• CAS No.: 1310-66-3
• Molecular Formula: LiOH^.H2O
• Molecular Weight: 41.9636
• Hs Code.: 2825201000
• European Community (EC) Number: 603-454-3,624-580-5
• ICSC Number: 0914
• UN Number: 2680
• UNII: G51XLP968G
• DSSTox Substance ID: DTXSID8051382
• Wikidata: Q12451415
• Mol file: 1310-66-3.mol

Synonyms:lithium hydroxide;lithium hydroxide monohydrate;lithium hydroxide, 6Li-labeled;lithium hydroxide, 7Li-labeled

Chemical Property of Lithium hydroxide monohydrate

Chemical Property:

• Appearance/Colour: colourless, hygroscopic crystals
• Melting Point: 462 °C
• Boiling Point: 100 °C at 760 mmHg
• PSA: 32.29000
• Density: 1.51 g/cm³
• LogP: -0.24110
• Water Solubility.: 109 g/L (20℃)
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 42.02930777
• Heavy Atom Count: 3
• Complexity: 2
• Transport DOT Label: Corrosive

Purity/Quality:

56.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C:Corrosive
• Statements: R20/22:; R35:
• Safety Statements: S22:; S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: [Li+].O.[OH-]
• Inhalation Risk: Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
• Effects of Short Term Exposure: The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation may cause lung oedema, but only after initial corrosive effects on eyes and/or airways have become manifest.

Technology Process of Lithium hydroxide monohydrate

There total 18 articles about Lithium hydroxide monohydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Li34.2MnN3.9O13.7 → lithium hydroxide monohydrate (1310-66-3) + manganese(II) oxide + lithium carbonate (554-13-2)

Guidance literature:

In neat (no solvent); stored in open air for 8 wk; detd. by X-ray diffraction;

DOI:10.1021/ic900082u

Reference yield:

Li7.9MnN3.2O1.6 → lithium manganese oxide + lithium hydroxide monohydrate (1310-66-3) + manganese(II) oxide + lithium carbonate (554-13-2)

Guidance literature:

In neat (no solvent); stored in open air for 8 wk; detd. by X-ray diffraction;

DOI:10.1021/ic900082u

Reference yield:

Li1.98Mn1.01Se1001O1.01 + water (7732-18-5) → manganese(II) selenide + manganese(II) hydroxide + lithium hydroxide monohydrate (1310-66-3) + lithium selenide (12136-60-6)

Guidance literature:

With air; at 20 ℃; for 0.5h;

DOI:10.1021/acs.inorgchem.8b01850

upstream raw materials:

water

lithium hydroxide

lithium carbonate

n-butyllithium

Downstream raw materials:

water

oxygen

Nitrogen dioxide

8-benzyloxy-2-hexyl-3-hydroxy-octanoic acid

Refernces

Complexes of a triazine-3-thione ligand with divalent metals: Crystal structure of [CdL₂DMF]₂·2DMF·1/4H ₂O

10.1016/j.poly.2005.03.093

The research investigates the synthesis and characterization of metal complexes formed with the ligand 5-methoxy-5,6-diphenyl-4,5-dihydro-2H-[1,2,4]triazine-3-thione (LH2OCH3) and various divalent metals including Cd(II), Zn(II), Pb(II), Co(III), and Ni(II). Lithium Hydroxide Monohydrate (LiOH·H2O) is used as a base to facilitate the deprotonation of the ligand LH2OCH3, enabling it to act as a monoanion and coordinate with metal ions. The purpose of the study is to explore the coordination chemistry of this ligand with different metals, understand its structural preferences, and assess its potential applications, particularly as a sensor for toxic Cd(II) ions. The ligand acts as a monoanion (L) in all complexes, losing its methoxy group in a basic medium and coordinating to metal ions through its sulfur atom and deprotonated amine nitrogen. The study concludes that the ligand forms dinuclear structures with Cd(II), Zn(II), and Pb(II), where sulfur atoms of two ligands bridge the metal ions, while Co(III) and Ni(II) form monomeric compounds. The electrochemical behavior of the cadmium complex shows promise for developing new sensors for Cd(II) ions.