1H,1H,2H,2H-PERFLUORODECANETHIOL

Base Information

• Chemical Name: 1H,1H,2H,2H-PERFLUORODECANETHIOL
• CAS No.: 34143-74-3
• Molecular Formula: C10H5 F17 S
• Molecular Weight: 480.189
• Hs Code.: 2930909090
• Mol file: 34143-74-3.mol

Synonyms:1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-Heptadecanefluoro-10-decanethiol;1,1,2,2-Tetrahydroperfluoro-1-decanethiol;1,1,2,2-Tetrahydroperfluorodecanethiol;1,1,2,2-Tetrahydroperfluorodecylmercaptan; 1-Mercapto-2-(perfluorooctyl)ethane;1H,1H,1H,2H-Perfluorodecanethiol; 1H,1H,2H,2H-Perfluorodecane-1-thiol;1H,1H,2H,2H-Perfluorodecanethiol; 2-(Perfluorooctyl)-1-ethanethiol;2-(Perfluorooctyl)ethanethiol;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-1-decanethiol; Lodyne 924

Chemical Property of 1H,1H,2H,2H-PERFLUORODECANETHIOL

Chemical Property:

• Vapor Pressure: 0.482mmHg at 25°C
• Melting Point: 15 °C
• Refractive Index: n20/D 1.333
• Boiling Point: 82 °C
• PKA: 9.61±0.10(Predicted)
• Flash Point: 75°C
• PSA: 38.80000
• Density: 1.597g/cm³
• LogP: 6.31570
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

1H,1H,2H,2H-Perfluorodecyl-1-thiol ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 1H, 1H, 2H, 2H-perfluorododecyl mercaptan is a perfluorinated organic substance and can be used as an organic reagent. PFDT can be used to modify the surface of polydopamine-silver (Ag) nanoparticle array for surface enhanced raman scattering detection. It can also be used as an anti-corrosive coating that blocks oxidation and gives lubricating properties on the surface of copper. SAMs based on PFDT with a high water contact angle of 120° and a work function of 5.44 eV were coated on gold (Au) electrodes which were used in the fabrication of N and P-typed organic thin film transistors.

Technology Process of 1H,1H,2H,2H-PERFLUORODECANETHIOL

There total 9 articles about 1H,1H,2H,2H-PERFLUORODECANETHIOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1,2-bis(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)disulfide (42977-21-9) → 1H,1H,2H,2H-Perfluorodecanethiol (34143-74-3)

Guidance literature:

With tributylphosphine; water; In tetrahydrofuran; at 20 ℃; for 9h; Inert atmosphere;

DOI:10.1039/c1ob05710c

Reference yield: 68.0%

S-[2-(perfluorooctyl)ethyl]thioacetate (125640-21-3) → 1H,1H,2H,2H-Perfluorodecanethiol (34143-74-3) + 1,2-bis(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)disulfide (42977-21-9)

Guidance literature:

With sodium hydroxide; In methanol; for 3h; Heating;

DOI:10.1016/S0022-1139(00)00215-3

Reference yield: 62.0%

2-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-decyl)-isothiourea; hydriodide → 1H,1H,2H,2H-Perfluorodecanethiol (34143-74-3)

Guidance literature:

With sodium hydroxide; In water; at 78 - 80 ℃; for 1h;

DOI:10.1016/S0022-1139(00)80097-4

upstream raw materials:

2-(n-perfluorooctyl)ethyl iodide

thiourea

S-[2-(perfluorooctyl)ethyl]thioacetate

1-iodoheptadecafluorooctane

Downstream raw materials:

3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylsulfanyl)-1-(4-methoxybenzyl)-1,3-dihydroindol-2-one

3-(4-chlorobut-2-enyl)-3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylsulfanyl)-1-(4-methoxybenzyl)-1,3-dihydroindol-2-one

6-methoxy-3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylsulfanyl)-1-p-methoxybenzyl-1,3-dihydroindol-2-one

C₂₇H₂₀F₁₇NO₃S

Refernces

• 1、 Coote, Susannah C.,Quenum, Seidjolo,Procter, David J.. "Exploiting Sm(ii) and Sm(iii) in SmI2-initiated reaction cascades: Application in a tag removal-cyclisation approach to spirooxindole scaffolds". . p. 5104 - 5108. Retrieved 2011/08/07.
• 2、 Naud,Calas,Blancou,Commeyras. "Synthesis of terminally perfluorinated long-chain alkanethiols, sulfides and disulfides from the corresponding halides". . p. 173 - 183. Retrieved 2007/10/03.