Diphenylarsine

Base Information

• Chemical Name: Diphenylarsine
• CAS No.: 829-83-4
• Molecular Formula: C12H10As
• Molecular Weight: 230.141
• European Community (EC) Number: 212-589-3
• DSSTox Substance ID: DTXSID90232075
• Nikkaji Number: J1.004.913J
• Mol file: 829-83-4.mol

Synonyms:Diphenylarsine;829-83-4;EINECS 212-589-3;Arsine, diphenyl-;Diphenylarsinoradical;C12H11As;C12-H11-As;DTXSID90232075

Chemical Property of Diphenylarsine

Chemical Property:

• Boiling Point: 288°Cat760mmHg
• Flash Point: 119.2°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 228.999845
• Heavy Atom Count: 13
• Complexity: 116

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[As]C2=CC=CC=C2

Technology Process of Diphenylarsine

There total 7 articles about Diphenylarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

triphenyl-arsane (603-32-7) → diphenylarsane (829-83-4)

Guidance literature:

triphenyl-arsane; With lithium; In tetrahydrofuran; at 0 - 20 ℃; for 3.08333h; Schlenk technique; Inert atmosphere;

With water; In tetrahydrofuran; at 0 ℃; for 0.0833333h; Schlenk technique; Inert atmosphere;

DOI:10.1021/jacs.6b03500

Reference yield: 77.9%

Natrium-diphenylarsenid (41006-64-8) + N,N-Bis(2-chloroethyl)-2-chlorpropylammonium-chlorid (1936-40-9) → diphenylarsane (829-83-4) + N,N-bis-(2-diphenylarsinoethyl)-2-diphenylarsinopropylamin

Guidance literature:

With ammonia; In tetrahydrofuran; at -70 ℃; for 1h;

DOI:10.1016/0022-328X(86)84033-5

Reference yield:

chlorodiphenylarsine (712-48-1) → diphenylarsane (829-83-4)

Guidance literature:

With lithium borohydride;

upstream raw materials:

trichlorodiphenylarsorane

chlorodiphenylarsine

diphenylarsinic acid

triphenyl-arsane

Downstream raw materials:

(β-Hydroxyethyl)diphenylarsan

1,2-bis(diphenylarsino)ethane

tetramethyldiarsine

tetraphenyl-diarsane

Refernces

• 1、 Roering, Andrew J.,Davidson, Jillian J.,MacMillan, Samantha N.,Tanski, Joseph M.,Waterman, Rory. "Mechanistic variety in zirconium-catalyzed bond-forming reaction of arsines". experimental part. p. 4488 - 4498. Retrieved 2009/02/04.