Diphenylchloroarsine

Base Information

• Chemical Name: Diphenylchloroarsine
• CAS No.: 712-48-1
• Molecular Formula: C12H10 As Cl
• Molecular Weight: 264.586
• Hs Code.: 2931900036
• European Community (EC) Number: 211-921-4
• ICSC Number: 1526
• UN Number: 1699
• UNII: 1H39V3559B
• DSSTox Substance ID: DTXSID30858733
• Nikkaji Number: J35.211J
• Wikipedia: Diphenylchlorarsine
• Wikidata: Q421470
• Mol file: 712-48-1.mol

Synonyms:Clark 1;diphenyl arsine chloride

Chemical Property of Diphenylchloroarsine

Chemical Property:

• Vapor Pressure: 0.000211mmHg at 25°C
• Melting Point: 44℃
• Refractive Index: 1.6332
• Boiling Point: 337°C at 760 mmHg
• Flash Point: 154.2°C
• PSA: 0.00000
• Density: 1.4820
• LogP: 2.03110
• Water Solubility.: 5.9(e)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 263.968698
• Heavy Atom Count: 14
• Complexity: 142
• Transport DOT Label: Poison

Purity/Quality:

99%一级, ^*data from raw suppliers

Safty Information:

• Pictogram(s): A poison. Toxic by inhalation, strong irritant to tissue.
• Hazard Codes: A poison. Toxic by inhalation, strong irritant to tissue.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[As](C2=CC=CC=C2)Cl
• Inhalation Risk: A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20 °C; on spraying or dispersing, however, much faster.
• Effects of Short Term Exposure: The substance is irritating to the eyes and skin. The substance may cause effects on the nervous system. Exposure at high levels could cause lowering of consciousness. Inhalation of high levels of the aerosol may cause lung oedema. The effects may be delayed. Exposure at high levels could cause death.

Technology Process of Diphenylchloroarsine

There total 57 articles about Diphenylchloroarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

→ chlorodiphenylarsine (712-48-1)

Guidance literature:

With hydrogenchloride;

Reference yield:

triphenyl-arsane (603-32-7) → dichlorophenylarsine (696-28-6) + chlorodiphenylarsine (712-48-1)

Guidance literature:

With arsenic trichloride; at 250 - 280 ℃; im Ruehrautoklaven;

Reference yield:

diphenylmercury(II) (587-85-9,1337-09-3) → dichlorophenylarsine (696-28-6) + chlorodiphenylarsine (712-48-1)

Guidance literature:

With arsenic trichloride; at 200 - 210 ℃;

upstream raw materials:

phosgene

diphenylarsane

ethanol

ethoxy-chloro-phenyl-arsine

Downstream raw materials:

4-trityl-1-(diphenylmethyl)benzene

tetraphenyl-diarsane

bis(diphenylarsenic) sulfide

fluoro-diphenyl-arsine

Refernces

• 1、 Forster, Glynis E.,Begley, Michael J.,Sowerby, D. Bryan. "Some Group 15 Pseudo-halides and the Crystal Structure of Diphenylbismuth(III) Thiocyanate". . p. 383 - 388. Retrieved 2007/10/02.
• 2、 Kauffmann, Thomas,Altepeter, Bruno,Klas, Norbert,Kriegesmann, Reinhard. "New Reagents, XXXIV. (Diphenylarsino)methyllithium: Synthesis and Preparative Applications". . p. 2353 - 2364. Retrieved 2007/10/02.