Allylsuccinic anhydride

Base Information

• Chemical Name: Allylsuccinic anhydride
• CAS No.: 7539-12-0
• Molecular Formula: C7H8 O3
• Molecular Weight: 140.139
• Hs Code.: 2917190090
• European Community (EC) Number: 231-412-0
• UNII: 23R9WQT6YO
• DSSTox Substance ID: DTXSID90996842
• Nikkaji Number: J54.354C
• Mol file: 7539-12-0.mol

Synonyms:Allylsuccinic anhydride;7539-12-0;3-Allyldihydrofuran-2,5-Dione;Succinic anhydride, allyl-;3-prop-2-enyloxolane-2,5-dione;Allyl succinic anhydride;3-Allyl(dihydro)furan-2,5-dione;4-Pentene-1,2-dicarboxylic Anhydride;BRN 0111959;EINECS 231-412-0;23R9WQT6YO;3-(prop-2-en-1-yl)oxolane-2,5-dione;EC 231-412-0;4-17-00-05922 (Beilstein Handbook Reference);(2-Propenyl)butanedioic Anhydride;UNII-23R9WQT6YO;allylsuccinic acid anhydride;allyl-succinic acid anhydride;SCHEMBL113660;Allylsuccinic Anhydride, 97%;3-Allyldihydro-2,5-furandione;DTXSID90996842;3-allyltetrahydrofuran-2,5-dione;MFCD00085227;AKOS006229982;ALLYL SUCCINIC ANHYDRIDE [INCI];BS-23470;3-Allyldihydro-2,5-furandione AldrichCPR;2,5-Furandione, dihydro-3-(2-propenyl)-;3-Allyldihydro-2,5-furandione, AldrichCPR;LS-147507;A1283;CS-0205172;FT-0622054;D88407;EN300-7338310;A838400;W-110226;2,5-FURANDIONE, DIHYDRO-3-(2-PROPEN-1-YL)-

Chemical Property of Allylsuccinic anhydride

Chemical Property:

• Vapor Pressure: 0.0177mmHg at 25°C
• Refractive Index: 1.4700-1.4720
• Boiling Point: 143 °C / 17mmHg
• Flash Point: 115.9°C
• PSA: 43.37000
• Density: 1.17
• LogP: 0.65220
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 140.047344113
• Heavy Atom Count: 10
• Complexity: 183

Purity/Quality:

98% ^*data from raw suppliers

Allylsuccinic Anhydride ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38-22
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCC1CC(=O)OC1=O

Technology Process of Allylsuccinic anhydride

There total 6 articles about Allylsuccinic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

allyl succinic acid (5754-10-9) → allylsuccinic anhydride (7539-12-0)

Guidance literature:

With acetyl chloride; for 3h; Heating;

DOI:10.1055/s-2000-7110

Reference yield: 41.0%

succinic acid anhydride (108-30-5) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → allylsuccinic anhydride (7539-12-0)

Guidance literature:

With 4-methoxy-phenol; dimethyltin dichloride; In toluene; at 175 - 200 ℃; for 12 - 48h; under 21307.1 - 32788.1 Torr; Reactivity;

Reference yield:

maleic anhydride (108-31-6) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → allylsuccinic anhydride (7539-12-0)

Guidance literature:

With benzene; at 250 ℃;

upstream raw materials:

maleic anhydride

propene

benzene

allyl succinic acid

Refernces

• 1、 Bergmeier,Ismail. "Synthesis of monosubstituted succinic acids from tert-butylsuccinate". . p. 1369 - 1371. Retrieved 2007/10/03.