Trimethyltin(1+)

Base Information

• Chemical Name: Trimethyltin(1+)
• CAS No.: 5089-96-3
• Molecular Formula: C3H9Sn+
• Molecular Weight: 163.814
• DSSTox Substance ID: DTXSID20198913
• Wikidata: Q27095763
• Mol file: 5089-96-3.mol

Synonyms:Trimethyltin ion;Trimethylstannylium;Trimethyltin(1+);Trimethyltin(1+) ion;Stannylium, trimethyl-;BRN 3903051;Tin(1+), trimethyl-, ion;Stannylium, trimethyl- (9CI);5089-96-3;trimethylstannanylium;trimethyltin cation;SnMe3Cl;(Trimethyl)stannane;C3H9Sn;C3-H9-Sn;DTXSID20198913;LS-153874;Q27095763

Chemical Property of Trimethyltin(1+)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 164.972628
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn+](C)C

Technology Process of Trimethyltin(1+)

There total 4 articles about Trimethyltin(1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(1,10-phenanthroline)ruthenium(III)(3+) (41673-52-3,23633-32-1,19694-32-7) + isobutyl-trimethyl stannane (1118-10-1) + acetonitrile (75-05-8,26809-02-9) → (Ru(N2C12H8)2(N2C12H7CH2CH(CH3)2))(2+) + N-tert-butylacetamide (762-84-5) + N-(2-butyl)ethanamide (1189-05-5) + N-isobutylacetamide (1540-94-9) + trimethylstannylium (5089-96-3)

Guidance literature:

In acetonitrile; byproducts: trans-2-butene, cis-2-butene; react. Ru(phen)3(3+) and i-BuSnMe3 in acetonitrile at 25°C;

DOI:10.1021/ja00369a030

Reference yield:

C36H21FeN9O6(3+) (22327-24-8) + isobutyl-trimethyl stannane (1118-10-1) + acetonitrile (75-05-8,26809-02-9) → N-tert-butylacetamide (762-84-5) + Fe(2+)*2N2C12H7NO2*N2C12H6(NO2)C4H9=(Fe(N2C12H7NO2)2(N2C12H6(NO2)CH2CH(CH3)2))(2+) + N-(2-butyl)ethanamide (1189-05-5) + N-isobutylacetamide (1540-94-9) + trimethylstannylium (5089-96-3)

Guidance literature:

In acetonitrile; byproducts: trans-2-butene, cis-2-butene; react. Fe(5-NO2phen)3(3+) and i-BuSnMe3 in acetonitrile at 25°C;

DOI:10.1021/ja00369a030

Reference yield:

tris(1,10-phenanthroline)ruthenium(III)(3+) (41673-52-3,23633-32-1,19694-32-7) + n-propyltrimethyltin (3531-45-1) + acetonitrile (75-05-8,26809-02-9) → (Ru(N2C12H8)2(N2C12H7C3H7))(2+) + n-propylacetamide (5331-48-6) + trimethylstannylium (5089-96-3)

Guidance literature:

In acetonitrile; react. Ru(phen)3(3+) and n-PrSnMe3 in acetonitrile at 25°C;

DOI:10.1021/ja00369a030

upstream raw materials:

tris(1,10-phenanthroline)ruthenium(III)⁽³⁺⁾

isobutyl-trimethyl stannane

acetonitrile

n-propyltrimethyltin

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