trimethyl(2-methylpropyl)stannane

Base Information

• Chemical Name: trimethyl(2-methylpropyl)stannane
• CAS No.: 1118-10-1
• Molecular Formula: C7H18 Sn
• Molecular Weight: 220.93
• Mol file: 1118-10-1.mol

Synonyms:Stannane,isobutyltrimethyl- (8CI); Tin, isobutyltrimethyl- (7CI);Isobutyltrimethylstannane; Isobutyltrimethyltin; Trimethylisobutyltin

Chemical Property of trimethyl(2-methylpropyl)stannane

Chemical Property:

• Vapor Pressure: 3.88mmHg at 25°C
• Boiling Point: 155.6°Cat760mmHg
• Flash Point: 41.2°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trimethyl(2-methylpropyl)stannane

There total 7 articles about trimethyl(2-methylpropyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trimethylstannyl sodium (16643-09-7) + isobutyryl chloride (513-36-0) → isobutyl-trimethyl stannane (1118-10-1)

Guidance literature:

In tetrahydrofuran; 0°C in N2-atmosphere; various yields for various conditions;

DOI:10.1021/ja00394a017

Reference yield: 100.0%

Isobutyl iodide (513-38-2) + trimethylstannyl sodium (16643-09-7) → isobutyl-trimethyl stannane (1118-10-1)

Guidance literature:

In tetrahydrofuran; 0°C in N2-atmosphere; various yields for various conditions;

DOI:10.1021/ja00394a017

Reference yield: 98.0%

Isobutyl bromide (78-77-3) + trimethylstannyl sodium (16643-09-7) → isobutyl-trimethyl stannane (1118-10-1)

Guidance literature:

In tetrahydrofuran; 0°C in N2-atmosphere; various yields for various conditions;

DOI:10.1021/ja00394a017

upstream raw materials:

trimethylstannyl sodium

isobutyryl chloride

Isobutyl iodide

Isobutyl bromide

Downstream raw materials:

(Z)-2-Butene

N-tert-butylacetamide

trans-2-Butene

4-Isobutyl-[1,10]phenanthroline

Refernces

• 1、 Kuivila, Henry G.,Reeves, William G.. "REACTIONS OF TRIMETHYLTINSODIUM WITH ALKYL HALIDES. EFFECTS OF STRUCTURE AND SOLVENT ON COURSE OF REACTION AND REACTIVITY". . p. 801 - 808. Retrieved 2007/10/02.