1,3-DIIMINOBENZ[F]ISOINDOLINE

Base Information

• Chemical Name: 1,3-DIIMINOBENZ[F]ISOINDOLINE
• CAS No.: 65558-69-2
• Molecular Formula: C12H9N3
• Molecular Weight: 195.224
• Hs Code.: 2933990090
• Mol file: 65558-69-2.mol

Synonyms:1,3-Diiminobenz[f]isoindoline;2,3-Dihydro-1,3-diimino-1H-benz[f]isoindole;

Chemical Property of 1,3-DIIMINOBENZ[F]ISOINDOLINE

Chemical Property:

• Vapor Pressure: 6.13E-07mmHg at 25°C
• Melting Point: 240°C (dec.) (lit.)
• Refractive Index: 1.761
• Boiling Point: 410.2 °C at 760 mmHg
• Flash Point: 201.9 °C
• PSA: 59.73000
• Density: 1.4 g/cm³
• LogP: 2.62200

Purity/Quality:

98% ^*data from raw suppliers

1,3-DiiminobenzIsoindoline ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 1,3-DIIMINOBENZ[F]ISOINDOLINE

There total 1 articles about 1,3-DIIMINOBENZ[F]ISOINDOLINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

2,3-dicyanonaphthalene (22856-30-0) → 1,3-diiminobenz[f]-isoindoline (65558-69-2)

Guidance literature:

With ammonia; sodium methylate; In methanol; 1.) 45 min; 2.) reflux, 3 h;

DOI:10.1021/ja00336a019

Reference yield: 13.0%

2-Ethylhexylamine (104-75-6) + ruthenium(III) chloride trihydrate (14898-67-0) + 1-imino-1H-benzo[f]isoindol-3-amine (65558-69-2) → bis(2-ethylhexylamine)(2,3-naphthalocyaninato)ruthenium(II)

Guidance literature:

With DBU; In 2-ethoxy-ethanol; N2; Ru-salt, DBU and 1-imino-1H-benz(f)-isoindol-3-amine was refluxed for 24 h in ethoxyethanol, cooled, poured into MeOH, precipitate filteredout, dried and washed (n-hexane), stirred with 2-ethylhexylamine for 1 h at 100°C; excess 2-ethylhexylamine removed under reduced pressure, chromd. (silica gel, CHCl3), dried (100°C, 0.01 Torr); elem. anal.;

upstream raw materials:

2,3-dicyanonaphthalene

Refernces

• 1、 Wheeler,Nagasubramanian,Bard,Schechtman,Dininny,Kenney. "SILICON PHTHALOCYANINE AND A SILICON NAPHTHALOCYANINE: SYNTHESIS, ELECTROCHEMISTRY, AND ELECTROGENERATED CHEMILUMINESCENCE.". . p. 7404 - 7410. Retrieved 2007/10/02.