Methanesulfonic acid, 1,1,1-trifluoro-, 5,8-dihydro-5,8-bis[(methoxymethoxy)methyl]-4-[[(4-methylphenyl)sulfon yl]amino]-3-(phenylmethoxy)-1-naphthalenyl ester

Base Information

Chemical Name:Methanesulfonic acid, 1,1,1-trifluoro-, 5,8-dihydro-5,8-bis[(methoxymethoxy)methyl]-4-[[(4-methylphenyl)sulfon yl]amino]-3-(phenylmethoxy)-1-naphthalenyl ester
CAS No.:925463-51-0
Molecular Formula:C31H34F3NO10S2
Molecular Weight:701.739
Hs Code.:

Methanesulfonic acid, 1,1,1-trifluoro-,
5,8-dihydro-5,8-bis[(methoxymethoxy)methyl]-4-[[(4-methylphenyl)sulfon
yl]amino]-3-(phenylmethoxy)-1-naphthalenyl ester

Synonyms:

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Chemical Property of Methanesulfonic acid, 1,1,1-trifluoro-, 5,8-dihydro-5,8-bis[(methoxymethoxy)methyl]-4-[[(4-methylphenyl)sulfon yl]amino]-3-(phenylmethoxy)-1-naphthalenyl ester

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Technology Process of Methanesulfonic acid, 1,1,1-trifluoro-, 5,8-dihydro-5,8-bis[(methoxymethoxy)methyl]-4-[[(4-methylphenyl)sulfon yl]amino]-3-(phenylmethoxy)-1-naphthalenyl ester

There total 11 articles about Methanesulfonic acid, 1,1,1-trifluoro-, 5,8-dihydro-5,8-bis[(methoxymethoxy)methyl]-4-[[(4-methylphenyl)sulfon yl]amino]-3-(phenylmethoxy)-1-naphthalenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 925463-49-6
N-(2-benzyloxy-4-hydroxy-5,8-bis-methoxymethoxymethyl-5,8-dihydro-naphthalen-1-yl)-4-methyl-benzenesulfonamide

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 925463-51-0
trifluoro-methanesulfonic acid 3-benzyloxy-5,8-bis-methoxymethoxymethyl-4-(toluene-4-sulfonylamino)-5,8-dihydro-naphthalen-1-yl ester

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; for 0.666667h;
DOI:10.1021/jo062064j

Reference yield:

: (2E,4E)-1,6-Bis-methoxymethoxy-hexa-2,4-diene

: 925463-51-0
trifluoro-methanesulfonic acid 3-benzyloxy-5,8-bis-methoxymethoxymethyl-4-(toluene-4-sulfonylamino)-5,8-dihydro-naphthalen-1-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: CH₂Cl₂ / 24 h / 9308660 Torr

2: 0.860 g / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 0.5 h

3: 98 percent / sodium hydride / tetrahydrofuran / 0.67 h / 0 - 20 °C

With sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane; 1: Diels-Alder reaction;
DOI:10.1021/jo062064j

Reference yield:

: 925463-43-0
4-amino-3-benzyloxy-phenol

: 925463-51-0
trifluoro-methanesulfonic acid 3-benzyloxy-5,8-bis-methoxymethoxymethyl-4-(toluene-4-sulfonylamino)-5,8-dihydro-naphthalen-1-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / pyridine / CH₂Cl₂ / 4 h / 20 °C

2: 96 percent / sodium periodate on silica gel / CH₂Cl₂ / 4 h

3: CH₂Cl₂ / 24 h / 9308660 Torr

4: 0.860 g / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 0.5 h

5: 98 percent / sodium hydride / tetrahydrofuran / 0.67 h / 0 - 20 °C

With pyridine; sodium periodate; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane; 3: Diels-Alder reaction;
DOI:10.1021/jo062064j