Dichloro-(2-cyclohex-3-en-1-ylethyl)-methylsilane

Base Information

• Chemical Name: Dichloro-(2-cyclohex-3-en-1-ylethyl)-methylsilane
• CAS No.: 17864-93-6
• Molecular Formula: C9H16Cl2Si
• Molecular Weight: 223.218
• Hs Code.: 2931900090
• European Community (EC) Number: 241-815-3
• DSSTox Substance ID: DTXSID20939106
• Nikkaji Number: J260.771I
• Mol file: 17864-93-6.mol

Synonyms:17864-93-6;dichloro-(2-cyclohex-3-en-1-ylethyl)-methylsilane;EINECS 241-815-3;2-(3-Cyclohexenyl)ethylmethyldichlorosilane;2-(4-CYCLOHEXENYL)ETHYLMETHYLDICHLOROSILANE;[2-(3-Cyclohexenyl)ethyl]methyldichlorosilane;Methyl(2-(3-cyclohexenyl)ethyl)dichlorosilane;Silane, dichloro(2-(3-cyclohexen-1-yl)ethyl)methyl-;Silane, dichloro[2-(3-cyclohexen-1-yl)ethyl]methyl-;Dichloro(2-(3-cyclohexen-1-yl)ethyl)methylsilane;Dichloro[2-(3-cyclohexen-1-yl)ethyl]methylsilane;[2-(4-CYCLOHEXENYL)ETHYL]METHYLDICHLOROSILANE;C9H16Cl2Si;C9-H16-Cl2-Si;dichloro(2-(cyclohex-3-en-1-yl)ethyl)(methyl)silane;SCHEMBL2101519;DTXSID20939106;MFCD00039471;FT-0637614;methyl-2-(3-cyclohexenyl)ethyldichlorosilane;dichloro(2-(cyclohex-3-enyl)ethyl)(methyl)silane;Dichloro[2-(3-cyclohexen-1-yl)ethyl](methyl)silane;dichloro[2-(cyclohex-3-en-1-yl)ethyl]methylsilane

Chemical Property of Dichloro-(2-cyclohex-3-en-1-ylethyl)-methylsilane

Chemical Property:

• Melting Point: <0°C
• Refractive Index: 1.4829
• Boiling Point: 244.4 °C at 760 mmHg
• Flash Point: 96.9 °C
• PSA: 0.00000
• Density: 1.051 g/cm³
• LogP: 4.28240
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 222.0398324
• Heavy Atom Count: 12
• Complexity: 166

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(4-CYCLOHEXENYL)ETHYLMETHYLDICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](CCC1CCC=CC1)(Cl)Cl

Technology Process of Dichloro-(2-cyclohex-3-en-1-ylethyl)-methylsilane

There total 2 articles about Dichloro-(2-cyclohex-3-en-1-ylethyl)-methylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dichloromethylsilane (75-54-7) + 4-ethenylcyclohexene (100-40-3) → dichloro-(2-cyclohex-3-enyl-ethyl)-methyl-silane (17864-93-6)

Guidance literature:

With platinum on activated charcoal;

DOI:10.1021/ja01561a054

Reference yield:

→ dichloro-(2-cyclohex-3-enyl-ethyl)-methyl-silane (17864-93-6)

Guidance literature:

4-Vinylcyclohexen, Methyldichlorsilan, H2PtCl6;

Reference yield:

dichloro-(2-cyclohex-3-enyl-ethyl)-methyl-silane (17864-93-6) + 4,4′-dibromo-2,2′-diiodo-5,5′-dimethoxy-1,1′-biphenyl (454182-36-6) → 2,7-dibromo-3,6-dimethoxy-9-methyl-9-[2-(cyclohex-3-en-1-yl)-ethyl]silafluorene

Guidance literature:

4,4′-dibromo-2,2′-diiodo-5,5′-dimethoxy-1,1′-biphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -110 ℃; for 1h; Inert atmosphere; Schlenk technique;

dichloro-(2-cyclohex-3-enyl-ethyl)-methyl-silane; In tetrahydrofuran; hexane; at -110 - 20 ℃; for 10h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ma401346y

upstream raw materials:

Dichloromethylsilane

4-ethenylcyclohexene

Downstream raw materials:

2,4,6,8-tetrakis-(2-cyclohex-3-enyl-ethyl)-2,4,6,8-tetramethyl-cyclotetrasiloxane

Refernces