2(5H)-Furanone, 5-[3-methyl-3-(phenylmethoxy)butyl]-

Base Information

• Chemical Name: 2(5H)-Furanone, 5-[3-methyl-3-(phenylmethoxy)butyl]-
• CAS No.: 92775-09-2
• Molecular Formula: C16H20O3
• Molecular Weight: 260.333
• Mol file: 92775-09-2.mol

Synonyms:

Chemical Property of 2(5H)-Furanone, 5-[3-methyl-3-(phenylmethoxy)butyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2(5H)-Furanone, 5-[3-methyl-3-(phenylmethoxy)butyl]-

There total 7 articles about 2(5H)-Furanone, 5-[3-methyl-3-(phenylmethoxy)butyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

(Z)-7-Benzyloxy-7-methyl-oct-2-ene-1,4-diol (92775-07-0) → 5-(3-Benzyloxy-3-methyl-butyl)-5H-furan-2-one (92775-09-2)

Guidance literature:

With Celite; silver carbonate; In benzene; for 7h; Heating;

DOI:10.1016/S0040-4039(01)81318-6

Reference yield:

2-methylpent-4-en-2-ol (624-97-5) → 5-(3-Benzyloxy-3-methyl-butyl)-5H-furan-2-one (92775-09-2)

Guidance literature:

Multi-step reaction with 6 steps

1: NaH

2: 1) B₂H₆, H₂O₂, 2) NaOH

3: PCC

5: 1) p-toluenesulfonic acid, 2) quinoline / Pd(O)/CaCO₃ / 1) CH₃OH

6: 75 percent / silver carbonate/celite / benzene / 7 h / Heating

With quinoline; sodium hydroxide; Celite; dihydrogen peroxide; sodium hydride; toluene-4-sulfonic acid; silver carbonate; pyridinium chlorochromate; diborane; Lindlar's catalyst; calcium carbonate; In benzene;

DOI:10.1016/S0040-4039(01)81318-6

Reference yield:

1-((2-methylpent-4-en-2-yloxy)methyl)benzene → 5-(3-Benzyloxy-3-methyl-butyl)-5H-furan-2-one (92775-09-2)

Guidance literature:

Multi-step reaction with 5 steps

1: 1) B₂H₆, H₂O₂, 2) NaOH

2: PCC

4: 1) p-toluenesulfonic acid, 2) quinoline / Pd(O)/CaCO₃ / 1) CH₃OH

5: 75 percent / silver carbonate/celite / benzene / 7 h / Heating

With quinoline; sodium hydroxide; Celite; dihydrogen peroxide; toluene-4-sulfonic acid; silver carbonate; pyridinium chlorochromate; diborane; Lindlar's catalyst; calcium carbonate; In benzene;

DOI:10.1016/S0040-4039(01)81318-6

upstream raw materials:

(Z)-7-Benzyloxy-7-methyl-oct-2-ene-1,4-diol

2-methylpent-4-en-2-ol

benzyl chloride

Downstream raw materials:

(4R,5S)-5-(3-Benzyloxy-3-methyl-butyl)-4-methyl-dihydro-furan-2-one