DI-MU-Chloro-dichlorobis(ethylene)diplatinum(II)

Base Information

• Chemical Name: DI-MU-Chloro-dichlorobis(ethylene)diplatinum(II)
• CAS No.: 12073-36-8
• Molecular Formula: C₄H₈Cl₄Pt₂
• Molecular Weight: 588.08
• European Community (EC) Number: 235-135-6
• Mol file: 12073-36-8.mol

Synonyms:12073-36-8;dichloroplatinum;ethene;DI-MU-CHLORO-DICHLOROBIS(ETHYLENE)DIPLATINUM(II);C4H8Cl4Pt2;[ptcl2(c2h4)]2;C4-H8-Cl4-Pt2;EINECS 235-135-6;MFCD00058713;SC10662;Di--chloro-dichlorobis(ethylene)diplatinum(II);Di-?-chloro-dichlorobis(ethylene)diplatinum(II);Di-mu-chlorodichlorobis(eta2-ethylene)diplatinum;Di- mu -chlorodichlorobis(ethylene)diplatinum(II)

Chemical Property of DI-MU-Chloro-dichlorobis(ethylene)diplatinum(II)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 4.35740
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C
• Sensitive.: air sensitive, moisture sensitiv
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 586.862539
• Heavy Atom Count: 10
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Di-μ-chloro-dichlorobis(ethylene)diplatinum(II), min. 97% Zeise's dimer ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=C.C=C.Cl[Pt]Cl.Cl[Pt]Cl

Technology Process of DI-MU-Chloro-dichlorobis(ethylene)diplatinum(II)

There total 1 articles about DI-MU-Chloro-dichlorobis(ethylene)diplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C2H5PtCl5(2-) (94986-03-5) → [(C2H4)PtCl2]2 (12144-54-6,12073-36-8,859026-66-7)

Guidance literature:

In tetradeuterioacetic acid; Irradiation (UV/VIS);

DOI:10.1016/0022-328X(84)85062-7

Reference yield:

trans-[PtCl2(ethene)]2 (12144-54-6,859026-66-7,12073-36-8) + ethene (74-85-1) → trans-dichloro-bis(ethene)platinum(II) (71423-58-0,859026-67-8,31781-68-7)

Guidance literature:

In acetone; Pt compd. reacted with C2H4 in acetone at -80°C; equilibrium;

DOI:10.1016/j.inoche.2006.04.006

Reference yield:

trans-[PtCl2(ethene)]2 (12144-54-6,859026-66-7,12073-36-8) + ethene (74-85-1) → cis-dichloro-bis(ethene)platinum(II) (859026-67-8,71423-58-0,31781-68-7)

Guidance literature:

In dichloromethane; Pt compd. reacted with C2H4 in CDCl3 at 298 K; observed by (1)H and (195)Pt NMR spectra and by UV spectra;

DOI:10.1016/j.inoche.2006.04.006

upstream raw materials:

C₂H₅PtCl₅^(2-)

Downstream raw materials:

trans-dichloro-bis(ethene)platinum(II)

cis-dichloro-bis(ethene)platinum(II)

Refernces

Bimetallic Systems. Part 11. Heterobimetallic and Unsymmetrical Diplatinum Complexes from cis- (dppm Angstroem Ph2PCH2PPh2; R = Me, 1-Naphthyl, or C6H4Me-o): Crystal Structure of <(C6H4Me-o)2Pt(μ-dppm)2PtMe2>

10.1039/DT9850001677

The research focuses on the synthesis and characterization of heterobimetallic and unsymmetrical diplatinum complexes derived from cis-[PtR,(dppm-P),] compounds, where dppm is Ph2PCH2PPh2 and R represents various organic groups. The purpose of the study was to explore the potential of these complexes for systematic synthesis of bimetallic compounds with a cis configuration around platinum, which would provide greater metal-metal separations and different conformational behavior compared to complexes with a trans configuration. The researchers successfully synthesized and characterized a series of complexes, including [(C6H4Me-o)2Pt(p-dppm)2PtMe2], [Me2Pt(p-dppm)2AgI], [Me2Pt(p-dppm)2AuCl], and [Me2Pt(p-dppm)2Ag]PF6, among others. The conclusions were drawn from detailed structural analysis, including X-ray diffraction studies, which confirmed the cis square-planar coordination at both platinum atoms and revealed the twist saddle conformation of the eight-membered R,P,C, ring. The study provided insights into the structural and conformational preferences of these complexes, with the Pt-Pt separation being the largest internuclear distance reported for a binuclear dppm complex.

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