Technology Process of Borane, dimethyl[2-(3-methyl-5-methylenecyclohexyl)ethyl]-
There total 1 articles about Borane, dimethyl[2-(3-methyl-5-methylenecyclohexyl)ethyl]- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
diethyl ether;
(Ar); to a soln. of 3,8-dimethyl-3-borabicyclo(4.3.1)decane was added at -65°C MeLi in ether; heating to 20°C, then cooled to -10 to 0°C; AcCl was added to the mixt.; stirred for 1 h at 0, then heated to 20°C; after removal of ether in a vac., hexane was added to the residue; filtration of the ppt., evapn. of the filtrate and distn. of the residue gave2-(3-methylene-5-methylcyclohex-1-yl)ethyl(dimethyl)borane; elem. anal.;
DOI:10.1016/0022-328X(84)80330-7
- Guidance literature:
-
With
sodium hydroxide; dihydrogen peroxide;
In
diethyl ether;
a) 20 deg C, 2 h, b) heating, 1 h;
DOI:10.1016/0022-328X(84)80330-7
