Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane

Base Information

Chemical Name:Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane
CAS No.:92813-85-9
Molecular Formula:C₁₃H₂₅B
Molecular Weight:192.153
Hs Code.:
DSSTox Substance ID:DTXSID30524426

Synonyms:92813-85-9;DTXSID30524426;Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane

Suppliers and Price of Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:192.2049310
Heavy Atom Count:14
Complexity:195

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C)(C)C(C)CC1CC(CC(=C)C1)C

Technology Process of Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane

There total 1 articles about Dimethyl[1-(3-methyl-5-methylidenecyclohexyl)propan-2-yl]borane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 92813-83-7
3,4,8-trimethyl-3-borabicyclo{4.3.1.}decane

: 917-54-4
methyllithium

: 75-36-5
acetyl chloride

: 92813-85-9
2-(3-methylene-5-methylcyclohex-1-yl)propyl(dimethyl)borane

Guidance literature:: In diethyl ether; (Ar); to a soln. of 3,4,8-trimethyl-3-borabicyclo(4.3.1)decane was added at -60°C MeLi in ether; heating to 20°C, then cooled to -10 to 0°C; AcCl was added to the mixt.; stirred for 1 h at 20°C; ether was distd. off, and pentane was added to the residue; the ppt. was filtered off, and the solvent was removed from the filtrate; distn. of the residue gave 2-(3-methylene-5-methylcyclohex-1-yl)propyl(dimethyl)borane; elem. anal.;
DOI:10.1016/0022-328X(84)80330-7

Reference yield: 54.0%

: 92813-85-9
2-(3-methylene-5-methylcyclohex-1-yl)propyl(dimethyl)borane

: 1-methylene-3-(2-hydroxypropyl)-5-methylcyclohexane

Guidance literature:: With sodium hydroxide; dihydrogen peroxide; In diethyl ether; a) 0 deg C, 1 h, b) 20 deg C, 2 h;
DOI:10.1016/0022-328X(84)80330-7

Reference yield:

: 92813-85-9
2-(3-methylene-5-methylcyclohex-1-yl)propyl(dimethyl)borane

: 1-methylene-3-(2-oxopropyl)-5-methylcyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: 54 percent / NaOH, 30percent aq. H₂O₂ / diethyl ether / a) 0 deg C, 1 h, b) 20 deg C, 2 h

2: 75 percent / pyridinechlorochromate, NaOAc / CH₂Cl₂ / 5 h / 20 °C

With sodium hydroxide; dihydrogen peroxide; sodium acetate; pyridinium chlorochromate; In diethyl ether; dichloromethane;
DOI:10.1016/0022-328X(84)80330-7