Coumithoate

Base Information

Chemical Name:Coumithoate
CAS No.:572-48-5
Molecular Formula:C₁₇H₂₁O₅PS
Molecular Weight:368.39
Hs Code.:
UNII:501C188SWN
DSSTox Substance ID:DTXSID1058131
Nikkaji Number:J6.543I
Wikidata:Q27260733
Mol file:572-48-5.mol

Synonyms:COUMITHOATE;Dition;Chromaphton;Coumithoate [ISO];Chromaphon;Dition Insecticide;Caswell No. 345A;572-48-5;ENT-24986;BRN 0049344;UNII-501C188SWN;7-Hydroxy-3,4-tetramethylenecoumarin O,O-diethyl thiophosphate;O,O-Diethyl O-(3,4-tetramethylenecoumarinyl-7) thiophosphate;501C188SWN;O,O-Diethyl 7-hydroxy-3,4-tetramethylene coumarinyl phosphorothioate;Diethyl 7,8,9,10-tetrahydro-6-oxobenzo(c)chroman-3-yl phosphorothioate;O,O-Diethyl O-(7,8,9,10-tetrahydro-6-oxobenzo(c)chroman-3-yl)phosphorothioate;O,O-Diethyl O-(7,8,9,10-tetrahydro-6-oxo-6H-dibenzo(b,d)pyran-3-yl) phosphorothioate;1-Cyclohexene-1-carboxylic acid, 2-(2,4-dihydorxyphenyl)-, delta-lactone, O,O-diethyl phosphorothioate;2-(2,4-Dihydroxyphenyl)-1-cyclohexene-1-carboxylic acid gamma-lactone O,O-diethyl phosphorothioate;4-18-00-00514 (Beilstein Handbook Reference);Phosphorothioic acid, O,O-diethyl O-(7,8,9,10-tetrahydro-6-oxo-6H-dibenzo(b,d)pyran-3-yl) ester;Phosporothioic acid, O,O-diethyl ester, O-ester with 7,8,9,10-tetrahydro-3-hydroxy-6H-dibenzo(b,d)pyran-6-one;1-Cyclohexene-1-carboxylic acid, 2-(2,4-dihydroxyphenyl)-, .delta.-lactone, O-ester with O,O-diethyl phosphorothioate;1-Cyclohexene-1-carboxylic acid, 2-(2,4-dihydroxyphenyl)-, delta-lactone, O-ester with O,O-diethyl phosphorothioate;Phosphorothioic acid, O,O-diethyl O-(7,8,9,10-tetrahydro-6-oxo-6H-dibenzo[b,d]pyran-3-yl) ester;ditione;Diethyl 7,8,9,10-tetrahydro-6-oxobenzo[c]chroman-3-yl phosphorothioate;PHOSPHOROTHIOIC ACID, O,O-DIETHYL ESTER, O-ESTER WITH 7,8,9,10-TETRAHYDRO-3-HYDROXY-6H-DIBENZO(B,D)PYRAN-6-ONE;Phosphorothioic acid, O,O-diethyl ester, O-ester with 7,8,9,10-tetrahydro-3-hydroxy-6H-dibenzo[b,d]pyran-6-one;COUMITHOATE [MI];SCHEMBL116666;C17H21O5PS;DTXSID1058131;C17-H21-O5-P-S;3-diethoxyphosphinothioyloxy-7,8,9,10-tetrahydrobenzo[c]chromen-6-one;LS-57431;Q27260733;O,O-Diethyl O-(6-oxo-7,8,9,10-tetrahydro-6H-benzo[c]chromen-3-yl) thiophosphate #;O,O-Diethyl O-(7,8,9,10-tetrahydro-6-oxo-6H-dibenzo(b,d)pyran-3-yl)phosphorothioate;O,O-DIETHYL O-(7,8,9,10-TETRAHYDRO-6-OXOBENZO(C)CHROMAN-3-YL) PHOSPHOROTHIOATE;1-CYCLOHEXENE-1-CARBOXYLIC ACID, 2-(2,4-DIHYDROXYPHENYL)-, .DELTA.-LACTONE, O,O-DIETHYL PHOSPHOROTHIOATE

Suppliers and Price of Coumithoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of Coumithoate

Chemical Property:

Vapor Pressure:1.36E-09mmHg at 25°C
Melting Point:88-88.5°
Boiling Point:485.9°Cat760mmHg
Flash Point:247.6°C
PSA：99.80000
Density:1.31g/cm³
LogP:4.99870
XLogP3:4.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:6
Exact Mass:368.08473194
Heavy Atom Count:24
Complexity:551

Purity/Quality:: 99.9% ^*data from raw suppliers

Safty Information:

Pictogram(s): T
Hazard Codes:T
Statements: 25
Safety Statements: 28-36/37-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOP(=S)(OCC)OC1=CC2=C(C=C1)C3=C(CCCC3)C(=O)O2
Uses Insecticide.

Technology Process of Coumithoate

There total 4 articles about Coumithoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3722-44-9
3-hydroxy-7,8,9,10-tetrahydrobenzo[c]chromen-6-one

: 572-48-5
3-diethoxythiophosphoryloxy-7,8,9,10-tetrahydro-benzo[c]chromen-6-one

Guidance literature:: Multi-step reaction with 3 steps

1: trichlorothiophosphine; triethylamine / 3 h / 0 °C

2: ethanol / 0 °C

3: ethanol

With trichlorothiophosphine; triethylamine; In ethanol;
DOI:10.1080/10286020.2015.1054815