gamma-Isomorphine

Base Information

• Chemical Name: gamma-Isomorphine
• CAS No.: 466-93-3
• Molecular Formula: C17H19NO3
• Molecular Weight: 285.343
• European Community (EC) Number: 207-378-8
• UNII: QSF4R6CR12
• DSSTox Substance ID: DTXSID50963616
• Nikkaji Number: J12.104E

Synonyms:gamma-Isomorphine;Pseudomorphine (C17 alkaloid);EINECS 207-378-8;UNII-QSF4R6CR12;QSF4R6CR12;466-93-3;Morphinan-3,8-diol, 6,7-didehydro-4,5-epoxy-17-methyl-, (5-alpha,8-beta)-;.GAMMA.-ISOMORPHINE;DTXSID50963616;LS-91751;Q27287475;17-Methyl-6,7-didehydro-4,5-epoxymorphinan-3,8-diol;MORPHINAN-3,8-DIOL, 6,7-DIDEHYDRO-4,5-EPOXY-17-METHYL-, (5.ALPHA.,8.BETA.)-;MORPHINAN-3,8.BETA.-DIOL, 6,7-DIDEHYDRO-4,5.ALPHA.-EPOXY-17-METHYL-

Chemical Property of gamma-Isomorphine

Chemical Property:

• Boiling Point: 480.7°Cat760mmHg
• Flash Point: 244.5°C
• Density: 1.44g/cm³
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 285.13649347
• Heavy Atom Count: 21
• Complexity: 494

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN1CCC23C4C=CC(C2C1CC5=C3C(=C(C=C5)O)O4)O
• Isomeric SMILES: CN1CC[C@]23[C@@H]4C=C[C@@H]([C@H]2[C@H]1CC5=C3C(=C(C=C5)O)O4)O

Technology Process of gamma-Isomorphine

There total 2 articles about gamma-Isomorphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6β-chloro-4,5α-epoxy-17-methyl-morphin-7-en-3-ol (60048-94-4) → γ-isomorphine (466-93-3)

Guidance literature:

With acetic acid;

Reference yield:

6-chloro-4,5-epoxy-17-methyl-morphin-7-en-3-ol (60048-94-4,63783-53-9) + acetic acid (64-19-7,77671-22-8) → morphine (143-70-4) + β-Isomorphin (466-94-4) + γ-isomorphine (466-93-3)

Guidance literature:

DOI:10.1021/ja01305a042

Reference yield:

dimethyl sulfate (77-78-1) + γ-isomorphine (466-93-3) → pseudocodeine (466-96-6)

Guidance literature:

With sodium methylate;

upstream raw materials:

6-chloro-4,5-epoxy-17-methyl-morphin-7-en-3-ol

acetic acid

6β-chloro-4,5α-epoxy-17-methyl-morphin-7-en-3-ol

Downstream raw materials:

3-ethoxy-4,5α-epoxy-17-methyl-morphin-6-en-8β-ol

pseudocodeine

17-methyl-morphinane-3,4,8β-triol

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