Bis[4-(phenylsulfanyl)phenyl]methanone

Base Information

• Chemical Name: Bis[4-(phenylsulfanyl)phenyl]methanone
• CAS No.: 93103-33-4
• Molecular Formula: C25H18OS2
• Molecular Weight: 398.549
• DSSTox Substance ID: DTXSID30536044
• Wikidata: Q82410555
• Mol file: 93103-33-4.mol

Synonyms:93103-33-4;Bis[4-(phenylsulfanyl)phenyl]methanone;SCHEMBL3282737;DTXSID30536044;AKOS005216491

Chemical Property of Bis[4-(phenylsulfanyl)phenyl]methanone

Chemical Property:

• XLogP3: 7.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 398.07990754
• Heavy Atom Count: 28
• Complexity: 423

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)SC2=CC=C(C=C2)C(=O)C3=CC=C(C=C3)SC4=CC=CC=C4

Technology Process of Bis[4-(phenylsulfanyl)phenyl]methanone

There total 4 articles about Bis[4-(phenylsulfanyl)phenyl]methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium thiophenolate (930-69-8) + 4,4'-Dichlorobenzophenone (90-98-2) → 4,4'-bis-phenylsulfanyl-benzophenone (93103-33-4)

Guidance literature:

N-2-ethylhexyl chloride of 4-dibutylaminopyridine; In toluene; at 110 ℃; for 2h;

DOI:10.1016/S0040-4039(01)91026-3

Reference yield:

diphenyl sulfide (139-66-2) → thio-xanthene-9-one (492-22-8) + 4,4'-bis-phenylsulfanyl-benzophenone (93103-33-4)

Guidance literature:

With carbon disulfide; phosgene; aluminium trichloride;

DOI:10.1021/jo01134a022

Reference yield:

bis(4-bromophenyl)methanone (3988-03-2) + thiophenol (108-98-5) → 4,4'-bis-phenylsulfanyl-benzophenone (93103-33-4)

Guidance literature:

With sodium methylate; copper; at 210 ℃;

upstream raw materials:

phosgene

diphenyl sulfide

bis(4-bromophenyl)methanone

thiophenol

Downstream raw materials:

4,4'-bis-benzenesulfonyl-benzophenone