(E)-1-Methoxy-1-butene

Base Information

• Chemical Name: (E)-1-Methoxy-1-butene
• CAS No.: 10034-13-6
• Molecular Formula: C5H10 O
• Molecular Weight: 86.1338
• Nikkaji Number: J590.736E,J102.078A
• Mol file: 10034-13-6.mol

Synonyms:(E)-1-Methoxy-1-butene;1-methoxy-1-butene;(E)-1-methoxybut-1-ene;trans-1-Methoxy-1-butene;(E)-CH3CH2CH=CH(OCH3);10034-13-6;Ether, 1-butenyl methyl;(E)-1-Methoxy-but-1-ene;(1E)-1-Butenyl methyl ether;KMQWOHBEYVPGQJ-SNAWJCMRSA-N

Chemical Property of (E)-1-Methoxy-1-butene

Chemical Property:

• Vapor Pressure: 153mmHg at 25°C
• Boiling Point: 68.2°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.775g/cm³
• LogP: 1.55650
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 86.073164938
• Heavy Atom Count: 6
• Complexity: 39.2

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=COC
• Isomeric SMILES: CC/C=C/OC

Technology Process of (E)-1-Methoxy-1-butene

There total 2 articles about (E)-1-Methoxy-1-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cis-1-methoxy-2-methylcyclopropane (36024-53-0,36024-54-1) → methane (34557-54-5,27936-85-2) + cis-1-methoxybut-1-ene (10034-12-5) + trans-1-methoxy-butene (10034-13-6) + ethane (74-84-0) + 1-methoxy-2-methylprop-1-ene (17574-84-4) + trans-1-methoxy-2-methylcyclopropane (36024-53-0,36024-54-1)

Guidance literature:

In gas; at 416.7 ℃; under 28 Torr; Kinetics; Rate constant; Thermodynamic data; further temperatures; variation of initial pressure; further fragmentation products;

DOI:10.1039/f19858101415

Reference yield:

trans-1-methoxy-2-methylcyclopropane (36024-53-0,36024-54-1) → methane (34557-54-5,27936-85-2) + cis-1-methoxybut-1-ene (10034-12-5) + trans-1-methoxy-butene (10034-13-6) + ethane (74-84-0) + 1-methoxy-2-methylprop-1-ene (17574-84-4) + cis-1-methoxy-2-methylcyclopropane (36024-53-0,36024-54-1)

Guidance literature:

In gas; at 416.7 ℃; under 28 Torr; Kinetics; Rate constant; Thermodynamic data; further temperatures; variation of initial pressure; further fragmentation products;

DOI:10.1039/f19858101415

Reference yield: 5.1%

Bu4 NCl hydrate + trans-1-methoxy-butene (10034-13-6) → Methyl (E)-2-pentenoate (15790-87-1,818-59-7,15790-88-2) + methyl (E)-pent-3-enoate (818-58-6)

Guidance literature:

palladium dichloride; In 1-methyl-pyrrolidin-2-one; CO;

upstream raw materials:

cis-1-methoxy-2-methylcyclopropane

trans-1-methoxy-2-methylcyclopropane

Downstream raw materials:

(3R,4R)-4-Ethyl-3-methoxy-2,2-diphenyl-cyclobutanone

Methyl (E)-2-pentenoate

methyl (E)-pent-3-enoate