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Ethane
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CAS NO.74-84-0 Ethane
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74-84-0 Usage

InChI:InChI=1S/C2H6/c1-2/h1-2H3

74-84-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (00582)  Ethane  ≥99.95% (GC) 74-84-0 00582-11L 945.36CNY Detail
Aldrich (539775)  Ethane  99.99% 74-84-0 539775-110G 6,966.18CNY Detail
Aldrich (768979)  Ethane  Messer® CANGas, 99.95% 74-84-0 768979-1L 1,105.65CNY Detail

74-84-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Ethane

1.2 Other means of identification

Product number -
Other names Dimethyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Fuels and fuel additives,Functional fluids (open systems),Intermediates,Ion exchange agents,Paint additives and coating additives not described by other categories,Pigments,Plasticizers,Processing aids, not otherwise listed
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:74-84-0 SDS

74-84-0Synthetic route

ethene
74-85-1

ethene

ethane
74-84-0

ethane

Conditions
ConditionsYield
With hydrogen; [Ru2(μ-O2C-C6H4-CO2)2] at 20℃; for 5.4h; Kinetics; Product distribution; Further Variations:; Catalysts; reaction times;100%
With [1,1-(1,3-dimethylimidazol-2-ylidene)(PPh3)-3-(Py)-1,2-RhSB9H8]; hydrogen In dichloromethane-d2 under 3750.38 Torr; for 12h; Catalytic behavior; Time; Inert atmosphere;73%
With hydrogen; palladium25%
triethyl borane
97-94-9

triethyl borane

N-Cyclohexylcyclododecylidenamin
79014-37-2

N-Cyclohexylcyclododecylidenamin

A

ethane
74-84-0

ethane

B

(Z/E)-(N-Cyclohexyl-1-cyclododecenylamino)diethylboran
74793-30-9

(Z/E)-(N-Cyclohexyl-1-cyclododecenylamino)diethylboran

Conditions
ConditionsYield
With diethylboryl-pivalate at 150℃; for 19h;A 100%
B 96%
With diethylboryl-pivalate at 110℃; for 24h; Product distribution; reactivity of 1h with pure diethyl(pivaloyloxy)borane, different reaction times;A 4.78 mmol
B n/a
tris(1,10-phenanthroline)iron(III)
13479-49-7

tris(1,10-phenanthroline)iron(III)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With oxygen In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) in presence of O2 at 298 K; monitored by (1)H-NMR;A <1
B <1
C 100%
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B <1
C 98%
tris(1,10-phenanthroline)iron(III)
13479-49-7

tris(1,10-phenanthroline)iron(III)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
With oxygen In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) in presence of O2 at 298 K; monitored by (1)H-NMR;A <1
B 100%
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(phen)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B 100%
cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With perchloric acid; oxygen In acetonitrile Kinetics; in presence of H2O;A <1
B 100%
tris(2,2'-bipyridine)iron(III) ion
18661-69-3

tris(2,2'-bipyridine)iron(III) ion

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

cis-{(C2H5)2Co(2,2'-bipyridine)2}(ClO4)

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(bpy)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B <1
C 100%
cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
With perchloric acid; oxygen In acetonitrile Kinetics; cleavage of the Co-C bond; slowly;A 100%
B <1
With perchloric acid; oxygen In acetonitrile Kinetics; enzyme-catalyzed oxidn. (samll amount of CH4); without HClO4 no catalytic activity;A 11%
B 89%
In acetonitrile Soln. of complex in MeCN in a sealed Pyrex tube was thermostated at 353 K in an oil bath for 52 h;; An atmospheric pressure of N2 was introduced to the tube; gaseous products were analysed by GLC;;
tris(2,2'-bipyridine)iron(III) ion
18661-69-3

tris(2,2'-bipyridine)iron(III) ion

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
In acetonitrile byproducts: {Co(2,2'-bipyridine)2}(2+); one-electron oxidn. of cis-Co complex by (Fe(bpy)3(3+) at 298 K; monitored by (1)H-NMR;A <1
B 100%
trans-(CH3)2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)

trans-(CH3)2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)

iodine
7553-56-2

iodine

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
In tetrachloromethane Irradiation (UV/VIS); Irradiation at 509 nm in CCl4; Estimation of the quantum yield of the photochemical reaction. Yield of the products estimated by g.l.c.;A 0.02%
B <1
C 100%
cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

A

Co(2,2'-bipyridine)(2+)
15878-94-1

Co(2,2'-bipyridine)(2+)

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
With ethenetetracarbonitrile In acetonitrile Kinetics; byproducts: tetracyanoethylene(1-); 298 K;A n/a
B 100%
With 2,3-dicyano-p-benzoquinone In acetonitrile Kinetics; byproducts: 2,3-dicyano-p-benzoquinone(1-); 298 K;A n/a
B 100%
With 2,6-dichloro-1,4-benzoquinone; magnesium(II) perchlorate In acetonitrile Kinetics; byproducts: 2,6-dichloro-p-benzoquinone(1-); 298 K;A n/a
B 96%
ethylzinc 2-hydroxymethylphenoxide

ethylzinc 2-hydroxymethylphenoxide

salicylic alcohol
90-01-7

salicylic alcohol

diethylzinc
557-20-0

diethylzinc

A

zinc bis(2-ethylzincoxyphenmethoxide)

zinc bis(2-ethylzincoxyphenmethoxide)

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
react. of the educts in a molar ration of 3:2;A n/a
B 100%
diethylzinc
557-20-0

diethylzinc

benzene-1,2-diol
120-80-9

benzene-1,2-diol

A

ethane
74-84-0

ethane

B

zinc pyrocatecholate
10586-34-2

zinc pyrocatecholate

Conditions
ConditionsYield
react. of the educts in a molar ratio of 1:1;A 100%
B n/a
potassium-2,2-(1,5-cyclooctandiyl)-4,5,5-triethyl-2,5-dihydro-3-methyl-1,2,5-oxoniadiboratolate
138517-78-9

potassium-2,2-(1,5-cyclooctandiyl)-4,5,5-triethyl-2,5-dihydro-3-methyl-1,2,5-oxoniadiboratolate

A

potassium 2,2-(1,5-cyclooctandiyl)-4,5-diethyl-2,5-dihydro-3-methyl-1,2,5-oxadiboratolate
138517-92-7

potassium 2,2-(1,5-cyclooctandiyl)-4,5-diethyl-2,5-dihydro-3-methyl-1,2,5-oxadiboratolate

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
In neat (no solvent) Ar atmosphere; heating (120-140°C, 1 h); elem. anal.;A 93%
B 100%
potassium 2,2,3,4,5,5-hexaethyl-2,5-dihydro-1,2,5-oxoniadiboratolate
138517-80-3

potassium 2,2,3,4,5,5-hexaethyl-2,5-dihydro-1,2,5-oxoniadiboratolate

A

potassium 2,2,3,4,5-pentaethyl-2,5-dihydro-1,2,5-oxadiboratolate
138517-94-9

potassium 2,2,3,4,5-pentaethyl-2,5-dihydro-1,2,5-oxadiboratolate

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
In neat (no solvent) Ar atmosphere; heating (110-115°C, 90 min); elem. anal.;A 100%
B 100%
Trimethylboroxine
823-96-1

Trimethylboroxine

methyl iodide
74-88-4

methyl iodide

ethane
74-84-0

ethane

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); cesium fluoride In tetrahydrofuran; N,N-dimethyl-formamide at 80℃; for 0.0833333h; Inert atmosphere; Schlenk technique;100%
oxalic acid
144-62-7

oxalic acid

ethane
74-84-0

ethane

Conditions
ConditionsYield
With 1,1,1,2,2,2-hexamethyldisilane; tris(pentafluorophenyl)borate In dichloromethane-d2 at 25℃; for 2h; Concentration; Reagent/catalyst; Solvent; Temperature; Time;100%
cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
With iodine In acetonitrile Kinetics; byproducts: I3(1-), (CH3Co(2,2'-bipyridine)2I)(1+); one-electron oxidn. of cis-Co complex by I2 at 298 K; monitored by (1)H-NMR and UV spect. (361 nm);A <1
B 0.6%
C 99%
cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

cis-{(CH3)2Co(2,2'-bipyridine)}(ClO4)

A

methyl bromide
74-83-9

methyl bromide

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

Conditions
ConditionsYield
With bromine In acetonitrile one-electron oxidn. of cis-Co complex by Br2 at 298 K; monitored by (1)H-NMR;A 99%
B <1
C 0.24%
cis-{Me2Co(2,2'-bipyridine)2}(1+)

cis-{Me2Co(2,2'-bipyridine)2}(1+)

iodine
7553-56-2

iodine

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
In tetrachloromethane Irradiation (UV/VIS); Irradiation at 509 nm in CCl4; Estimation of the quantum yield of the photochemical reaction. Yield of the products are estimated by g.l.c.;A <1
B 0.9%
C 99%
trans-(CH3)2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)

trans-(CH3)2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

methyl iodide
74-88-4

methyl iodide

Conditions
ConditionsYield
With iodine In acetonitrile Kinetics; byproducts: I3(1-); one-electron oxidn. of trans-Co complex by I2 at 298 K; monitored by (1)H-NMR and UV spect. (361 nm);A 0.34%
B 0.06%
C 99%
trans-(CH3)2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)

trans-(CH3)2Co(11-hydroxy-2,3,9,10-tetramethyl-1,4,8,11-tetraazaundeca-1,3,8,10-tetraen-1-olate)

A

methyl bromide
74-83-9

methyl bromide

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

Conditions
ConditionsYield
With bromine In acetonitrile one-electron oxidn. of trans-Co complex by Br2 at 298 K; monitored by (1)H-NMR;A 99%
B 0.15%
C <1
acetylene
74-86-2

acetylene

ethane
74-84-0

ethane

Conditions
ConditionsYield
With hydrogen; Pd/Ag-type catalyst supported on alumina at 30℃; under 750.075 Torr;98.2%
With 5% Pd/C; hydrogen at 49.84℃; for 1h; Catalytic behavior; Gas phase; chemoselective reaction;93%
With hydrogen; palladium/alumina at 80℃; under 300.02 Torr; effect of acetylene pressure on the reaction selectivity and hydrogenation rate; in excess of ethylene;
Diethyl methylphosphonate
683-08-9

Diethyl methylphosphonate

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

lithium ethyl methylphosphonate

lithium ethyl methylphosphonate

D

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With lithium In neat (no solvent) at 140℃; Further byproducts given. Yields of byproduct given;A n/a
B n/a
C 98.2%
D n/a
lithium triethylheptynylgallate
80359-11-1

lithium triethylheptynylgallate

A

ethane
74-84-0

ethane

B

1-iodo-hept-1-yne
54573-13-6

1-iodo-hept-1-yne

Conditions
ConditionsYield
With iodine In benzene at 20℃; for 3h;A 97%
B 98%
carbon monoxide
201230-82-2

carbon monoxide

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

propane
74-98-6

propane

D

carbon dioxide
124-38-9

carbon dioxide

E

water

water

Conditions
ConditionsYield
With hydrogen; nickel at 329.9℃; nickel powder, prepared by evaporation-condensation; Yields of byproduct given;A 98%
B n/a
C n/a
D n/a
E n/a
triethylborane-pyrazole adduct

triethylborane-pyrazole adduct

Trimethylacetic acid
75-98-9

Trimethylacetic acid

A

ethane
74-84-0

ethane

B

C9H19BO2*C3H4N2

C9H19BO2*C3H4N2

Conditions
ConditionsYield
In n-heptane at 15 - 50℃; for 3h; Esterification;A n/a
B 98%
ethyl bromide
74-96-4

ethyl bromide

trans-NiMe2(triethylphosphine)2
60542-85-0, 81131-93-3

trans-NiMe2(triethylphosphine)2

trans-dibromobis(triethylphosphine)nickel(II)
69460-30-6, 19224-77-2

trans-dibromobis(triethylphosphine)nickel(II)

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

Conditions
ConditionsYield
In toluene ethyl bromide added into toluene soln. of NiMe2(PEt3)2, stirred at roomtemp. for 24 h; evapd. in vac., crystd. from Et2O-hexane; GLC anal.;A 66%
B 53%
C 117 %
D 98%
potassium 2,2,3,5,5-pentaethyl-2,5-dihydro-4-methyl-1,2,5-oxoniadiboratolate
138517-76-7

potassium 2,2,3,5,5-pentaethyl-2,5-dihydro-4-methyl-1,2,5-oxoniadiboratolate

A

potassium 2,2,4,5-tetraethyl-2,5-dihydro-3-methyl-1,2,5-oxadiboratolate
138517-89-2

potassium 2,2,4,5-tetraethyl-2,5-dihydro-3-methyl-1,2,5-oxadiboratolate

B

potassium 2,2,3,5-tetraethyl-2,5-dihydro-4-methyl-1,2,5-oxadiboratolate
138517-90-5

potassium 2,2,3,5-tetraethyl-2,5-dihydro-4-methyl-1,2,5-oxadiboratolate

C

ethane
74-84-0

ethane

Conditions
ConditionsYield
In neat (no solvent) Ar atmosphere; heating (120°C, 5 min); isomer mixt. not sepd.; ratio 3-methyl-/4-methyl-isomer 70/30; elem. anal.;A n/a
B n/a
C 98%
potassium 1,5-cyclooctanediylethylhydroxoborate
137669-91-1

potassium 1,5-cyclooctanediylethylhydroxoborate

sodium triethylborohydride

sodium triethylborohydride

A

(1,5-cyclooctanediylboryloxy)sodium
137669-80-8

(1,5-cyclooctanediylboryloxy)sodium

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
In 1,2,5-trimethyl-benzene Ar atmosphere; heating (100-120°C, 30 min); filtration, repeated washing (pentane), drying (0.001 Torr); elem. anal.;A 83%
B 98%
triethyl borane
97-94-9

triethyl borane

N-Cyclohexylidencyclododecylamin
79014-38-3

N-Cyclohexylidencyclododecylamin

A

ethane
74-84-0

ethane

B

diethylboran
79014-48-5

diethylboran

Conditions
ConditionsYield
With diethylboryl-pivalate at 100 - 105℃; for 4h; Yield given;A 97%
B n/a
ethane
74-84-0

ethane

ethylene dibromide
106-93-4

ethylene dibromide

Conditions
ConditionsYield
With 2AlBr3*CBr4; bromine at 55 - 65℃; for 18h;100%
With 2AlBr3*CBr4; bromine at 55 - 65℃; for 18h; Product distribution; Mechanism; different times;100%
ethane
74-84-0

ethane

ethene
74-85-1

ethene

Conditions
ConditionsYield
With oxygen; V-Mo-Nb-Te oxide98%
at 800℃; under 760.051 Torr; for 1h; Catalytic behavior; Gas phase; Flow reactor;84%
With disulfur; iron(II,III) oxide at 940℃; Reagent/catalyst; Temperature; Flow reactor;75.9%
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