2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate

Base Information

Chemical Name:2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate
CAS No.:93645-32-0
Molecular Formula:C₁₆H₂₀O₅
Molecular Weight:292.332
Hs Code.:
DSSTox Substance ID:DTXSID20538951
Wikidata:Q82414533

Synonyms:93645-32-0;2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate;DTXSID20538951

Suppliers and Price of 2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate

Chemical Property:

XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:6
Exact Mass:292.13107373
Heavy Atom Count:21
Complexity:417

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C(=C(C(=C1OC(=O)C)C)CC(=O)C)OC(=O)C)C

Technology Process of 2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate

There total 1 articles about 2,3,5-Trimethyl-6-(2-oxopropyl)-1,4-phenylene diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-24-7
acetic anhydride

: 93645-32-0
(3,6-diacetoxy-2,4,5-trimethylphenyl)acetone

Guidance literature:: With sulfuric acid;
DOI:10.1021/ja01858a036

Reference yield:

: 93645-32-0
(3,6-diacetoxy-2,4,5-trimethylphenyl)acetone

: 151-50-8
potassium cyanide

: 118017-22-4
Acetic acid 4-acetoxy-2-(2-cyano-2-hydroxy-2-methyl-ethyl)-3,5,6-trimethyl-phenyl ester

Guidance literature:: With sulfuric acid; In water; dimethyl sulfoxide; at 3 - 5 ℃; for 1h;
DOI:10.1021/jo00264a012

Reference yield:

: 93645-32-0
(3,6-diacetoxy-2,4,5-trimethylphenyl)acetone

: 118017-26-8
all-rac-5-(benzyloxy)-2,4,6,7-tetramethyl-2,3-dihydrobenzofuran-2-carbaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 6 N H₂SO₄ / dimethylsulfoxide; H₂O / 1 h / 3 - 5 °C

2: HCl / 18 h / 70 °C

3: 70 percent / LiAlH₄ / diethyl ether / 1 h / 25 °C

4: 74.7 percent / K₂CO₃ / dimethylformamide / 24 h / 25 °C

5: 33 percent / CrO₃, pyridine / CH₂Cl₂ / 0.67 h / 25 °C

With pyridine; chromium(VI) oxide; hydrogenchloride; lithium aluminium tetrahydride; sulfuric acid; potassium carbonate; In diethyl ether; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1021/jo00264a012