(nitroperoxy)methane

Base Information

• Chemical Name: (nitroperoxy)methane
• CAS No.: 42829-59-4
• Molecular Formula: CH3NO4
• Molecular Weight: 93.0391
• DSSTox Substance ID: DTXSID30962723
• Wikidata: Q82944469
• Mol file: 42829-59-4.mol

Synonyms:(nitroperoxy)methane;42829-59-4;CH3OONO2;methyl peroxynitrate;CH3O2NO2;Peroxynitric acid, methyl ester;DTXSID30962723

Chemical Property of (nitroperoxy)methane

Chemical Property:

• Vapor Pressure: 92.2mmHg at 25°C
• Boiling Point: 81.1°Cat760mmHg
• Flash Point: 37.4°C
• Density: 1.318g/cm³
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 93.00620758
• Heavy Atom Count: 6
• Complexity: 46

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COO[N+](=O)[O-]

Technology Process of (nitroperoxy)methane

There total 3 articles about (nitroperoxy)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetylperoxy radical (36709-10-1) → methyl nitrite (624-91-9) + acetyloxyl radical (13799-69-4) + peroxyacetyl nitrate (2278-22-0) + methylperoxy radical (2143-58-0) + methyl peroxynitrate (42829-59-4) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

With oxygen; nitrogen(II) oxide; chlorine; at -45.1 - 79.9 ℃; Mechanism; Rate constant; Irradiation;

DOI:10.1021/jp960792c

Reference yield:

methyl nitrite (624-91-9) + (Z)-azomethane (4143-42-4,503-28-6) → methyl nitrate (598-58-3) + methyl peroxynitrate (42829-59-4) + CH3NO7S

Guidance literature:

With sulfur dioxide; oxygen; In gas; Mechanism; Irradiation;

DOI:10.1021/j150609a011

Reference yield:

methyl nitrite (624-91-9) + (Z)-azomethane (4143-42-4,503-28-6) → methyl nitrate (598-58-3) + methyl peroxynitrate (42829-59-4)

Guidance literature:

In gas; Mechanism; Irradiation;

DOI:10.1021/j150609a011

upstream raw materials:

methyl nitrite

(Z)-azomethane

acetylperoxy radical

Downstream raw materials:

methyl nitrite