Methyl nitrite

Base Information

• Chemical Name: Methyl nitrite
• CAS No.: 624-91-9
• Molecular Formula: CH3 N O2
• Molecular Weight: 61.0403
• European Community (EC) Number: 210-870-5
• UN Number: 2455
• UNII: 96TLP8RN37
• DSSTox Substance ID: DTXSID8060795
• Nikkaji Number: J4.485G
• Wikipedia: Methyl_nitrite
• Wikidata: Q2730177
• Mol file: 624-91-9.mol

Synonyms:methyl nitrite

Chemical Property of Methyl nitrite

Chemical Property:

• Appearance/Colour: gas
• Vapor Pressure: 2790mmHg at 25°C
• Melting Point: -16 C
• Refractive Index: 1.3418 (estimate)
• Boiling Point: -12 C
• PSA: 38.66000
• Density: 1.1g/cm³
• LogP: 0.31420
• XLogP3: 0
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 61.016378338
• Heavy Atom Count: 4
• Complexity: 20
• Transport DOT Label: Forbidden

Purity/Quality:

98%min ^*data from raw suppliers

NITROUS ACID METHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Severe explosion risk when shocked or heated. Toxic by inhalation, narcotic.
• Hazard Codes: Severe explosion risk when shocked or heated. Toxic by inhalation, narcotic.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Nitrates and Nitrites
• Canonical SMILES: CON=O
• Uses: Synthesis of nitrile and nitroso esters.

Technology Process of Methyl nitrite

There total 102 articles about Methyl nitrite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9,10-dimethoxy-1,4:5,8-dimethano-1,2,3,4,5,6,7,8-octahydroanthracene (322732-78-5,157870-40-1) → methyl nitrite (624-91-9) + 1,4:5,8-dimethano-1,2,3,4,5,6,7,8-octahydro-9,10-anthraquinone (93433-97-7)

Guidance literature:

With Nitrogen dioxide; In dichloromethane; for 0.0833333h; Ambient temperature;

Reference yield: 99.9%

methanol (67-56-1) → methyl nitrite (624-91-9)

Guidance literature:

With nitric acid; fullerene-C₆₀; In water; at 70 ℃; under 760.051 Torr; Reagent/catalyst; Temperature; Concentration; Catalytic behavior; Inert atmosphere;

Reference yield: 98.9%

methanol (67-56-1) + nitrogen(II) oxide (10102-43-9) → methyl nitrite (624-91-9)

Guidance literature:

With oxygen; at 30 ℃; for 5.55556E-06h; under 375.038 Torr; Pressure; Temperature; Time;

upstream raw materials:

brucine

methanol

1-hexyl nitrite

cyclopentyl nitrite

Downstream raw materials:

ethyl 2-hydroxyimino-3-oxobutanoate

4-nitro-1-methylnaphthalene

2-nitro-1-methylnaphthalene

5-nitro-1-methylnaphthalene

Refernces

• 1、 Aldred, S. Elaine,Williams, D. Lyn H.. "Direct Measurement of the Rate Constants in the Reaction of Nitrous Acid with Methanol". . p. 73 - 74. Retrieved 1980.
• 2、 Caralp, Francoise,Rayez, Marie-Therese,Forst, Wendell,Gomez, Nathalie,Delcroix, Bruno,Fittschen, Christa,Devolder, Pascal. "Kinetic and mechanistic study of the pressure and temperature dependence of the reaction CH3O + NO". . p. 3321 - 3330. Retrieved 1998.
• 3、 Sirois, M.,Holmes, J. L.,Hop, C. E. C. A.. "Low-energy Fragmentations of Five Isomeric +* Ions". . p. 167 - 173. Retrieved 1990.
• 4、 Baranov, Vladimir,Petrie, Simon,Bohme, Diethard K.. "Methyl-cation shuttles: Xe- and N2-catalyzed isomerization of CH3NO2- to CH3ONO-". . p. 4500 - 4501. Retrieved 1996.
• 5、 Andersen, Lene L?ffler,?sterstr?m, Freja From,Sulbaek Andersen, Mads P.,Nielsen, Ole John,Wallington, Timothy J.. "Atmospheric chemistry of cis-CF3CH=CHCl (HCFO-1233zd(Z)): Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O3". . p. 289 - 293. Retrieved 2015.
• 6、 Chauvel, J. Paul,Conboy, Claire B.,Chew, Wilbert M.,Matson, Gerald B.,Spring, Cheryl A.,et al.. "Conformational kinetics of methyl nitrite. I. NMR spectral evidence for statistical intramolecular vibrational redistribution". . p. 1469 - 1476. Retrieved 1984.
• 7、 Ramakrishna, Rao,Symons, Martyn C. R.. "RADICAL CATIONS OF ORGANIC NITRO-DERIVATIVES". . p. 1293 - 1296. Retrieved 1983.
• 8、 Ghosh, Pradip N.,Guenthard, Hs. H.. "Infrared matrix spectra, normal coordinate analysis and valence force field of six isotopomers of methyl nitrite". . p. 1055 - 1066. Retrieved 1981.
• 9、 Wallington,Hoard,Sulbaek Andersen,Hurley,Nakano,Kawasaki. "Formation of Methyl Nitrite and Methyl Nitrate during Plasma Treatment of Diesel Exhaust". . p. 4242 - 4245. Retrieved 2003.
• 10、 Petrov,Chesnokov,Gorelik,Straub,Szarmes,Madey. "15N Isotope-selective infrared multiphoton dissociation of nitromethane by a free electron laser". . p. 719 - 722. Retrieved 1998.