Silane, (6-iodo-1-hexynyl)trimethyl-

Base Information

• Chemical Name: Silane, (6-iodo-1-hexynyl)trimethyl-
• CAS No.: 94012-71-2
• Molecular Formula: C9H17ISi
• Molecular Weight: 280.224
• DSSTox Substance ID: DTXSID60439352
• Nikkaji Number: J1.318.861K
• Wikidata: Q82255284
• Mol file: 94012-71-2.mol

Synonyms:Silane, (6-iodo-1-hexynyl)trimethyl-;94012-71-2;SCHEMBL9769619;DTXSID60439352;HSAQLCYXWUZPLZ-UHFFFAOYSA-N;6-iodo-1-trimethylsilylhex-1-yne;1-(Trimethylsilyl)-6-iodo-1-hexyne

Chemical Property of Silane, (6-iodo-1-hexynyl)trimethyl-

Chemical Property:

• Boiling Point: 91-93 °C(Press: 0.3 Torr)
• PSA: 0.00000
• Density: 1.303±0.06 g/cm3(Predicted)
• LogP: 3.47250
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 280.01442
• Heavy Atom Count: 11
• Complexity: 155

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C#CCCCCI

Technology Process of Silane, (6-iodo-1-hexynyl)trimethyl-

There total 3 articles about Silane, (6-iodo-1-hexynyl)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

(5-bromo-pent-1-ynyl)-trimehyl-silane (91656-99-4) → 1-(trimethylsilyl)-1-hexyne (3844-94-8) + trimethyl(6-iodo-1-hexynyl)silane (94012-71-2) + trimethyl(cyclopentylidenemethyl)silane (94012-70-1) + Trimethyl<(cyclopentylidene)iodomethyl>silane (122471-48-1)

Guidance literature:

With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; samarium diiodide; In tetrahydrofuran; for 24h; Ambient temperature;

DOI:10.1016/0040-4020(95)00703-B

Reference yield: 1.5%

(5-bromo-pent-1-ynyl)-trimehyl-silane (91656-99-4) → 1-(trimethylsilyl)-1-hexyne (3844-94-8) + trimethyl(6-iodo-1-hexynyl)silane (94012-71-2) + trimethyl(cyclopentylidenemethyl)silane (94012-70-1)

Guidance literature:

With samarium diiodide; In tetrahydrofuran; for 24h; Heating;

DOI:10.1016/0040-4020(95)00703-B

Reference yield:

1-chloro 4-iodobutane (10297-05-9) + trimethylsilylacetylene (1066-54-2) → trimethyl(6-iodo-1-hexynyl)silane (94012-71-2) + (6-chlorohex-1-yn-1-yl)trimethylsilane (113964-33-3)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1.) THF, hexane, -20 deg C, 2.) r.t, 90 h;

DOI:10.1016/S0040-4020(01)89857-4

upstream raw materials:

1-chloro 4-iodobutane

trimethylsilylacetylene

(5-bromo-pent-1-ynyl)-trimehyl-silane

Downstream raw materials:

dimethyl 2'-(6-(trimethylsilyl)-5-hexynyl)homophthalate

triphenyl(6-(trimethylsilyl)-5-hexynyl)phosphonium iodide

1-phenyl-1,7-nonadiyn-9-ol

3-(phenylsulfonyl)-1,2-nonadien-8-yne