Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate

Base Information

Chemical Name:Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate
CAS No.:94286-39-2
Molecular Formula:C20H30O4Si
Molecular Weight:362.541
Hs Code.:
DSSTox Substance ID:DTXSID70535617
Wikidata:Q82409968

Synonyms:94286-39-2;Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate;DTXSID70535617

Suppliers and Price of Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:9
Exact Mass:362.19133597
Heavy Atom Count:25
Complexity:444

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(C(=O)OCC)C1(CCCC1)[Si](C)(C)C2=CC=CC=C2

Technology Process of Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate

There total 1 articles about Diethyl {1-[dimethyl(phenyl)silyl]cyclopentyl}propanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 41589-42-8
2-cyclopentylidenemalonic acid diethyl ester

: 94286-39-2
diethyl 2-<1-(dimethylphenylsilyl)cyclopentyl>malonate

Guidance literature:: In tetrahydrofuran; at -23 ℃; for 3h;

Reference yield: 75.0%

: 94286-39-2
diethyl 2-<1-(dimethylphenylsilyl)cyclopentyl>malonate

: 94286-41-6
ethyl (1-phenyldimethylsilylcyclopentyl)acetate

Guidance literature:: With water; lithium chloride; In dimethyl sulfoxide; for 0.75h; Heating;

Reference yield:

: 94286-39-2
diethyl 2-<1-(dimethylphenylsilyl)cyclopentyl>malonate

: 94286-57-4
1-dimethyl(phenyl)silylcyclopentylethene

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / lithium chloride, water / dimethylsulfoxide / 0.75 h / Heating

2: 98 percent / lithium aluminium hydride / diethyl ether / 1 h / Ambient temperature

3: 1.) tri-n-butylphosphine, o-nitrophenylselenocyanate, 2.) pyridine, hydrogen peroxide / 1.) THF, room temperature, 1 h, 2.) 24 h

With pyridine; lithium aluminium tetrahydride; ortho-nitrophenyl selenocyanate; tributylphosphine; water; dihydrogen peroxide; lithium chloride; In diethyl ether; dimethyl sulfoxide;