(R)-(+)-Bornylamine

Base Information

Chemical Name:(R)-(+)-Bornylamine
CAS No.:464-42-6
Molecular Formula:C10H19 N
Molecular Weight:153.268
Hs Code.:
European Community (EC) Number:251-076-9
DSSTox Substance ID:DTXSID30947530
Nikkaji Number:J1.251.144B
ChEMBL ID:CHEMBL3735331
Mol file:464-42-6.mol

Synonyms:(R)-(+)-Bornylamine;32511-34-5;(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine;(+)-bornylamine;SCHEMBL542034;Bicyclo(2.2.1)heptan-2-amine, 1,7,7-trimethyl-, (1R-endo)-;CHEMBL3735331;(R)-(+)-Bornylamine, 97%;DTXSID30947530;MDFWXZBEVCOVIO-WEDXCCLWSA-N;AKOS015915781;AS-81150;(R)-(+)-Bornylamine, purum, >=97.0% (NT)

Suppliers and Price of (R)-(+)-Bornylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine
100mg
$ 350.00

Total 7 raw suppliers

Chemical Property of (R)-(+)-Bornylamine

Chemical Property:

Boiling Point:188.7°Cat760mmHg
PKA:10.17(at 25℃)
Flash Point:48.5°C
PSA：26.02000
Density:0.923g/cm³
LogP:2.86020
XLogP3:2.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:153.151749610
Heavy Atom Count:11
Complexity:185

Purity/Quality:

99% ^*data from raw suppliers

1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC1(C(C2)N)C)C
Isomeric SMILES:C[C@@]12CC[C@@H](C1(C)C)C[C@@H]2N

Technology Process of (R)-(+)-Bornylamine

There total 7 articles about (R)-(+)-Bornylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: (1S,4S)-N-benzyl-1,7,7-trimethylbicycto[2,2.1]heptan-2-amine

: 464-42-6,2223-67-8,4481-88-3,32511-34-5,32511-35-6,37606-04-5,94319-59-2,122038-71-5,128574-40-3
(1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine

Guidance literature:: With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 4h; under 775.743 Torr;

Reference yield:

: 24393-70-2
isoborneol

: 464-15-3
bornane

: 736109-58-3,787517-91-3,68546-28-1
1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

: 2223-67-8
1,7,7-trimethylbicyclo[2.2.1]heptan-exo-2-amine

: 6627-72-1
rac-endo-borneol

: 464-42-6
(1S,2R,4S)-1,7,7-Trimethyl-bicyclo[2.2.1]hept-2-ylamine

Guidance literature:: With ammonia; hydrogen; RPFIC; Product distribution; other substrate, other temperature;
DOI:10.1007/BF00958285

Reference yield:

: 464-48-2,68546-28-1
(1S)-camphor

: 464-42-6,2223-67-8,4481-88-3,32511-34-5,32511-35-6,37606-04-5,94319-59-2,122038-71-5,128574-40-3
(1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine

Guidance literature:: Multi-step reaction with 3 steps

1: toluene-4-sulfonic acid / toluene / 12 h / 130 °C / Inert atmosphere

2: sodium tetrahydroborate; nickel dichloride / methanol / 12 h / 0 - 20 °C

3: palladium 10% on activated carbon; hydrogen / methanol / 4 h / 20 °C / 775.74 Torr

With sodium tetrahydroborate; palladium 10% on activated carbon; hydrogen; toluene-4-sulfonic acid; nickel dichloride; In methanol; toluene;