Chloro(3-formyl-2-hydroxy-5-nitrophenyl)mercury

Base Information

• Chemical Name: Chloro(3-formyl-2-hydroxy-5-nitrophenyl)mercury
• CAS No.: 96194-54-6
• Molecular Formula: C7H4ClHgNO4
• Molecular Weight: 402.156
• DSSTox Substance ID: DTXSID50542849
• Wikidata: Q82419639
• Mol file: 96194-54-6.mol

Synonyms:96194-54-6;Chloro(3-formyl-2-hydroxy-5-nitrophenyl)mercury;DTXSID50542849

Chemical Property of Chloro(3-formyl-2-hydroxy-5-nitrophenyl)mercury

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 402.953529
• Heavy Atom Count: 14
• Complexity: 234

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=C(C=C(C(=C1C=O)O)[Hg]Cl)[N+](=O)[O-]

Technology Process of Chloro(3-formyl-2-hydroxy-5-nitrophenyl)mercury

There total 2 articles about Chloro(3-formyl-2-hydroxy-5-nitrophenyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

3-(acetoxymercurio)-5-nitrosalicylaldehyde (96194-53-5) → 3-(chloromercurio)-5-nitrosalicylaldehyde (96194-54-6)

Guidance literature:

With HCl; In potassium hydroxide; aq. KOH; dissolution of (HO)C6H2(CHO)(NO2)(HgOCOMe) in aq. KOH, dropwise addn. of concd. HCl for neutralization; ppt. washed with H2O, dried at 75°C for 24 h; elem. anal.;

DOI:10.1021/ja00297a062

Reference yield:

5-Nitrosalicylaldehyde (97-51-8) → 3-(chloromercurio)-5-nitrosalicylaldehyde (96194-54-6)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide; acetic acid

2: HCl / potassium hydroxide

With HCl; In potassium hydroxide; acetic acid;

DOI:10.1021/ja00297a062

upstream raw materials:

3-(acetoxymercurio)-5-nitrosalicylaldehyde

5-Nitrosalicylaldehyde