3-(acetoxymercurio)-5-nitrosalicylaldehyde

Base Information

• Chemical Name: 3-(acetoxymercurio)-5-nitrosalicylaldehyde
• CAS No.: 96194-53-5
• Molecular Formula: C₉H₇HgNO₆
• Molecular Weight: 425.748
• Mol file: 96194-53-5.mol

Synonyms:3-(acetoxymercurio)-5-nitrosalicylaldehyde

Chemical Property of 3-(acetoxymercurio)-5-nitrosalicylaldehyde

Chemical Property:

Purity/Quality:

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Technology Process of 3-(acetoxymercurio)-5-nitrosalicylaldehyde

There total 1 articles about 3-(acetoxymercurio)-5-nitrosalicylaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury(II) diacetate (1600-27-7) + 5-Nitrosalicylaldehyde (97-51-8) → 3-(acetoxymercurio)-5-nitrosalicylaldehyde (96194-53-5)

Guidance literature:

In potassium hydroxide; acetic acid; aq. KOH; aq. acetic acid; HOC6H3(CHO)(NO2) was heated in aq. KOH (0.03 M) at 70 °C, soln. of Hg(O2CMe)2 in aq. MeCO2H (0.08 M) was added over a 30-min period; filtered from hot soln., washed with MeCO2H (0.08 M), H2O, MeOH, Et2O, recrystd. from aq. MeCO2H; elem. anal.;

DOI:10.1021/ja00297a062

Reference yield: 42.0%

3-(acetoxymercurio)-5-nitrosalicylaldehyde (96194-53-5) → 3-(chloromercurio)-5-nitrosalicylaldehyde (96194-54-6)

Guidance literature:

With HCl; In potassium hydroxide; aq. KOH; dissolution of (HO)C6H2(CHO)(NO2)(HgOCOMe) in aq. KOH, dropwise addn. of concd. HCl for neutralization; ppt. washed with H2O, dried at 75°C for 24 h; elem. anal.;

DOI:10.1021/ja00297a062

upstream raw materials:

mercury(II) diacetate

5-Nitrosalicylaldehyde

Downstream raw materials:

3-(chloromercurio)-5-nitrosalicylaldehyde