methyl 2,3,6-tri-O-benzoylhexopyranoside

Base Information

• Chemical Name: methyl 2,3,6-tri-O-benzoylhexopyranoside
• CAS No.: 6344-46-3
• Molecular Formula: C28H26O9
• Molecular Weight: 506.5006
• Mol file: 6344-46-3.mol

Synonyms:

Chemical Property of methyl 2,3,6-tri-O-benzoylhexopyranoside

Chemical Property:

• Vapor Pressure: 1.17E-18mmHg at 25°C
• Boiling Point: 666.2°Cat760mmHg
• Flash Point: 220.3°C
• Density: 1.35g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl 2,3,6-tri-O-benzoylhexopyranoside

There total 74 articles about methyl 2,3,6-tri-O-benzoylhexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

benzoyl chloride (98-88-4) + methyl-alpha-D-glucopyranoside (97-30-3) → methyl 2,3,6-tri-O-benzoyl-α-D-glucopyranoside (57784-06-2,6344-46-3) + methyl 2,6-di-O-benzoyl-α-D-glycopyranoside (26927-44-6)

Guidance literature:

methyl-alpha-D-glucopyranoside; With di(n-butyl)tin oxide; In toluene; benzene; Heating;

benzoyl chloride; In toluene; at 100 ℃; for 0.5h;

DOI:10.1016/S0040-4020(02)00661-0

Reference yield: 90.3%

C29H26O10 → methyl 2,3,6-tri-O-benzoyl-α-D-glucopyranoside (57784-06-2,6344-46-3)

Guidance literature:

With triethylamine; In methanol; at 20 ℃; for 1h;

DOI:10.1021/acs.orglett.6b02675

Reference yield: 90.0%

C37H46O9Si (356060-80-5,356060-82-7) → methyl 2,3,6-tri-O-benzoyl β-D-galactopyranoside (6344-46-3)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃;

DOI:10.1016/S0040-4039(01)00611-6

upstream raw materials:

benzoyl chloride

methyl 2,3-di-O-benzoyl-β-D-glucopyranoside

C₆H₇O(OCOC₆H₅)3(O(C₃H₇)3Si)(OCH₃)

methyl 2,3,6-tri-O-benzoyl-4-O-(trifluoromethylsulfonyl)-β-D-galactopyranoside

Downstream raw materials:

methyl 2,3,6-tri-O-benzoyl-4-deoxy-4-thiocyanato-β-D-glucopyranoside

C₃₄H₂₉BrO₁₁S

methyl 2,3,6-tri-O-benzoyl-4-O-(imidazol-1-ylthiocarbonyl)-α-D-galactopyranoside

3-fluoro-3-deoxy-α-D-glucose