1H-Purine, 6-[(triphenylstannyl)thio]-

Base Information

• Chemical Name: 1H-Purine, 6-[(triphenylstannyl)thio]-
• CAS No.: 96692-60-3
• Molecular Formula: C₂₃H₁₈N₄SSn
• Molecular Weight: 501.199
• DSSTox Substance ID: DTXSID00405359
• Wikidata: Q82209866
• Mol file: 96692-60-3.mol

Synonyms:1H-Purine, 6-[(triphenylstannyl)thio]-;96692-60-3;DTXSID00405359

Chemical Property of 1H-Purine, 6-[(triphenylstannyl)thio]-

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 502.027420
• Heavy Atom Count: 29
• Complexity: 472

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)SC4=NC=NC5=C4NC=N5

Technology Process of 1H-Purine, 6-[(triphenylstannyl)thio]-

There total 1 articles about 1H-Purine, 6-[(triphenylstannyl)thio]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

6-mercaptopurine (50-44-2) + triphenyltin chloride (639-58-7) → triphenyl(6-thiopurinyl)tin(IV) (96692-60-3)

Guidance literature:

With sodium methoxide; In methanol; under N2; ligand (1 equiv.) added to soln. of NaOMe in MeOH; stirred for30 min; Ph3SnCl (1 equiv.) added; reacted at 60°C for 12 h; cool ed to room temp.; filtered; solvent removed gradually from filtrate by evapn. under vac.; recrystd. from MeOH; elem. anal.;

DOI:10.1016/j.ica.2004.03.002

upstream raw materials:

6-mercaptopurine

triphenyltin chloride