Diethyl 4-methoxybenzene-1,2-dicarboxylate

Base Information

Chemical Name:Diethyl 4-methoxybenzene-1,2-dicarboxylate
CAS No.:97025-36-0
Molecular Formula:C13H16O5
Molecular Weight:252.267
Hs Code.:
DSSTox Substance ID:DTXSID20550355
Nikkaji Number:J3.313.868G
Wikidata:Q82429654

Synonyms:97025-36-0;Diethyl 4-methoxybenzene-1,2-dicarboxylate;4-METHOXY-1,2-BENZENEDICARBOXYLIC ACID DIETHYL ESTER;diethyl 4-methoxyphthalate;DTXSID20550355;AKOS005216815

Suppliers and Price of Diethyl 4-methoxybenzene-1,2-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Diethyl 4-methoxybenzene-1,2-dicarboxylate

Chemical Property:

XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:7
Exact Mass:252.09977361
Heavy Atom Count:18
Complexity:289

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=C(C=C(C=C1)OC)C(=O)OCC

Technology Process of Diethyl 4-methoxybenzene-1,2-dicarboxylate

There total 3 articles about Diethyl 4-methoxybenzene-1,2-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 62415-74-1
3,4-dibromoanisole

: 541-41-3
chloroformic acid ethyl ester

: 97025-36-0
methoxy-4 phtalate d'ethyle

Guidance literature:: 3,4-dibromoanisole; With indium(III) chloride; chloro-trimethyl-silane; zinc; at 50 ℃; for 2h; Inert atmosphere;

chloroformic acid ethyl ester; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; at -30 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201205169

Reference yield:

: 5368-81-0
methyl 3-methoxybenzoate

: 97025-36-0
methoxy-4 phtalate d'ethyle

Guidance literature:: Multi-step reaction with 3 steps

1: 39 percent / chloral

2: 88 percent / KMnO₄, OH^(1-)

3: 86 percent

With potassium permanganate; hydroxide; chloral;
DOI:10.1016/0223-5234(87)90054-7